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प्रश्न
Write the order of reactivity of alkyl halides with ammonia.
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उत्तर
The order of reactivity of alkyl halides with ammonia is, R–I > R–Br > R–Cl.
संबंधित प्रश्न
Illustrate the following reaction giving suitable example in each case:Gabriel phthalimide synthesis
Give the structures of A, B and C in the following reactions :
Accomplish the following conversion:
Nitrobenzene to benzoic acid
Accomplish the following conversion:
Benzamide to toluene
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH + Br2] C}\]
Give the structure of A, B and C in the following reaction:
\[\ce{C6H5NO2 ->[Fe/HCl] A ->[NaNO2 + HCl][273 K] B ->[H2O/H+][\Delta] C}\]
Give the structures of A, B and C in the following reactions :
Account for the following:
Gabriel phthalimide synthesis is not preferred for preparing aromatic primary amines.
Choose the most correct option.
Which of the following compounds will dissolve in aqueous NaOH after undergoing reaction with Hinsberg reagent?
Answer in one sentence.
Which amide does produce ethanamine by Hofmann bromamide degradation reaction?
Answer the following
Explain the ammonolysis of alkyl halides.
Write reactions to prepare ethanamine from Acetonitrile.
Mendius reaction is used to convert _____________
Explain the following reaction with a suitable example.
Hofmann elimination reaction
Identify compound 'B' in following series of reactions?
\[\ce{Acetonitrile ->[Na/alcohol] A ->[NaNO2/dil.HCI] B}\]
The end product C of the following reaction is
\[\ce{C2H5NH2 ->[HNO2] A ->[PCl5] B ->[NH3][Alcohol] C}\]
Identify the product obtained, when benzamide is treated with bromine and aqueous sodium hydroxide.
Identify the product obtained when benzyl chloride undergoes ammonolysis in presence of excess ammonia followed by the reaction with two moles of methyl iodide.
____________ can be prepared exclusively by Gabriel phthalimide synthesis.
Identify the INCORRECT statement regarding Hofmann bromamide reaction.
Given below are two statements labelled as Assertion (A) and Reason (R).
Assertion (A): Alkyl halides are insoluble in water.
Reason (R): Alkyl halides have halogen attached to sp3 hybrid carbon.
Select the most appropriate answer from the options given below:
Which of the following reagents would not be a good choice for reducing an aryl nitro compound to an amine?
The best reagent for converting, 2-phenylpropanamide into 1- phenylethanamine is ______.
Hoffmann Bromamide Degradation reaction is shown by ______.
The reagents that can be used to convert benzenediazonium chloride to benzene are:
(i) \[\ce{SnCl2/HCl}\]
(ii) \[\ce{CH3CH2OH}\]
(iii) \[\ce{H3PO2}\]
(iv) \[\ce{LiAlH4}\]
What is the best reagent to convert nitrile to primary amine?
Write following conversions:
nitrobenzene `->` acetanilide
Write following conversions:
acetanilide `->` p-nitroaniline
How will you bring out the following conversion?
How will you carry out the following conversion?
How will you carry out the following conversions?
Describe Gabriel's phthalimide synthesis. (Give reaction)
Account for the following:
Aniline cannot be prepared by the ammonolysis of chlorobenzene under normal conditions.
A primary amine is formed by an amide on treatment with bromine and alkali. The primary amine has
Ethylamine can be prepared by the action of bromine and caustic potash on which compound?
Reduction of nitro alkanes yields which compound?
Which of the following compound is expected to be most basic?
C6H5CONHCH3 can be converted into C6H5CH2NHCH3 by:-
When primary amines are treated with HCl, the product obtained is which of the following?
Which of the following CANNOT be prepared by ammonolysis of alkyl halide?
Give reasons for the following:
Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.
- Phenyl methenamine
- N, N - Dimethylaniline
- N - Methyl aniline
- Benzenamine
Choose the correct order of the basic nature of the above amines.
What is the IUPAC name of \[\ce{(CH3)2 - N - CH3}\]?
Which of the following would not be a good choice for reducing nitrobenzene to aniline?
Write short note on the following:
Ammonolysis
Write a short note on the following:
Ammonolysis
Write the name of reduction product formed when ethyl cyanide is treated with sodium and alcohol.
Write short note on the following:
Ammonolysis
Assertion: Amimonolysis of alkyl halides involves the reaction between alkyl halides and alcoholic ammonia.
Reason: Ammonolysis of alkyl halides produces secondary amines only.
Write a short note on the following:
Ammonolysis.
Write short notes on the following:
Ammonolysis
Write a short note on the following:
Ammonolysis
