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JEE Main Chemistry (JEE Main) Syllabus: Check the Latest Syllabus

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JEE Main Chemistry (JEE Main) Syllabus 2026 PDF Download

Candidates must be familiar with the JEE Main Chemistry (JEE Main) Syllabus to pursue further Chemistry (JEE Main) education. Click here to access the JEE Main Chemistry (JEE Main) Syllabus 2026 PDF.


JEE Main Chemistry (JEE Main) Syllabus 2026

The JEE Main Chemistry (JEE Main) Syllabus for the JEE Main 2026 is available by the National Testing Agency. The JEE Main Chemistry (JEE Main) Syllabus is available for review from the link below. The JEE Main 2026 Chemistry (JEE Main) syllabus defines and describes each unit covered on the JEE Main 2026 Chemistry (JEE Main) exam.

Academic year:
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Syllabus

1 Some Basic Concepts in Chemistry
2 States of Matter
3 Atomic Structure
4 Chemical Bonding and Molecular Structure
  • Concept of Chemical Bonding  
    • Definition: Chemical Bond
  • Kossel and Lewis Approach to Chemical Bonding  
    • Kossel and Lewis theory
    • Lewis symbols
    • Significance of Lewis symbols
    • Lewis symbols and valence of elements
  • Kossel-lewis Approach to Chemical Bonding - Octet Rule  
  • Kossel-lewis Approach to Chemical Bonding - Covalent Bond  
    • Covalent bond
      a) Formation of chlorine molecule
      b) Formation of water molecule
    • Types of covalent bonds: Single, Double and Triple bond
    • Conditions for formation of covalent bond
      i) Number of valence electrons
      ii) Electronegativity difference
      iii) Small decrease in energy
  • Lewis Structures (Lewis Representation of Simple Molecules)  
  • Kossel-lewis Approach to Chemical Bonding - Formal Charge  
    • Formal charge (F.C.)
    • Assigning formal charge
  • Kossel-lewis Approach to Chemical Bonding - Limitations of the Octet Rule  
    • Limitations of the octet rule
    1. The incomplete octet of the central atom
    2. The expanded octet
    3. Odd-electron molecules
    4. Shape and geometry of a molecule
    5. Other drawbacks of the octet theory
  • Ionic or Electrovalent Bond  
    • Definition: Ion
    • Definition: Cation
    • Definition: Anion
    • Definition: Electropositive Element
    • Definition: Electronegative Element
    • Definition: Electrovalent Bond
    • Definition: Electrovalent (or Ionic) Compounds
    • Definition: Electrovalency
  • Bond Parameters  
    • Bond Parameters
    • Bond length
    • Bond order
    • Bond angle
    • Bond enthalpy
    • Resonance
    • Bond Length  
      • Bond length
      • Factors affecting bond length
      • Types of atomic radii
        i) Covalent radius
        ii) van der Waals radius
      • Average bond length for some single, double and triple bonds
    • Bond Angle  
      • Bond angle
      • Factors affecting the bond angle
    • Bond Enthalpy  
      • Bond enthalpy (Bond dissociation energy)
      • Bond enthalpy for polyatomic molecules
      • Factors affecting bond enthalpy
    • Bond Order  
  • Valence Shell Electron Pair Repulsion Theory (VSEPR)  
    • VSEPR theory
    • Main postulates of VSEPR theory
    • Geometry of some molecules
    • Geometry of some molecules
    • Steps to predict the molecular geometry using VSEPR theory
  • Valence Bond Theory  
    • Postulates of Valence Bond Theory
    • Interacting forces during covalent bond formation
      i) Force of repulsion
      ii) Force of attraction
    • Formation of hydrogen molecule on the basis of valence bond theory (VBT)
    • Overlap of atomic orbitals
    • Limitation of VBT
  • Valence Bond Theory - Orbital Overlap Concept  
    • Sigma and Pi bonds
    • Formation of hydrogen (H2) Molecule 
    1. Formation of fl uorine molecule (F2)
    2. Formation of HF molecule
    3. Formation of oxygen molecule (O2)
  • Valence Bond Theory - Directional Properties of Bonds  
  • Valence Bond Theory - Overlapping of Atomic Orbitals  
  • Valence Bond Theory - Types of Overlapping and Nature of Covalent Bonds  
    • Types of overlap of atomic orbitals
    1. Axial overlap: s-s overlap, s-p overlap, p-p overlap 
    2. Lateral overlap: p-p overlap
  • Valence Bond Theory - Strength of Sigma (σ) bond and pi (π) bond  
    • Difference between sigma (σ) bond and pi (π) bond
  • Hybridisation  
    • Hybridisation - Introduction  
      • Salient features of hybridisation, Important conditions for hybridisation
      • Types of hybridisation and geometry of molecules
      • Bonding in Ethylene
      • Formation of sigma bond
      • Formation of Pi (π ) bond
      • Bonding in acetylene
    • Types of Hybridisation  
      • sp, sp2, sp3, dsp2, sp3d, dsp3, sp3d2 or d2sp3
  • Molecular Orbital Theory - Introduction  
  • Molecular Orbital Theory  
    • Formation of molecular orbitals
    • Conditions for the combination of Atomic Orbitals
    • Types of molecular orbitals
    • Energy levels and electronic configuration
    • Key ideas of MO theory
    • MO description of simple diatomic Molecules
    • Conditions for the Combination of Atomic Orbitals  
      • Conditions for Atomic orbital (AO) to form Molecular orbital (MO)
      • Difference between AO and MO
    • Energy Level Diagram for Molecular Orbitals  
      • Relative energies of M.O. and filling of electrons
    • Electronic Configuration and Molecular Behaviour  
      • Stability of Molecules
        i) Stability of molecules in terms of bonding and antibonding electrons
        ii) Stability of molecules in terms of bond order
      • Bond order
      • Nature of the bond
      • Bond-length
      • Magnetic nature
  • Bonding in Some Homonuclear Diatomic Molecules  
    • Homonuclear diatomic molecules
    • Electronic configuration, bond order, and magnetic nature of some diatomic molecules
    1. Hydrogen molecule (H2)
    2. Helium molecule (He2)
    3. Lithium molecule (Li2)
    4. Carbon molecule (C2)
    5. Oxygen molecule (O2)
    • Heteronuclear diatomic molecules
    • Bond Energy
  • Hydrogen Bonding - Introduction  
    • Intramolecular Hydrogen Bond
    • Intermolecular hydrogen bond
  • Hydrogen Bonding  
    • Cause of Formation of Hydrogen Bond  
    • Types of Hydrogen Bonding  
      • Types of hydrogen bonding
      1. Intermolecular hydrogen bond
      2. lntramolecular hydrogen bond (Chelation)
  • Chemical Bonding and Molecular Structure Numericals  
  • Periodic Properties  
  • Shapes of Simple Molecules  
  • The Covalent Bond  
    • Definition: Covalent Compound
    • Definition: Covalent Molecule
    • Key Points: The Covalent Bond
  • Elementary Idea of Metallic Bonding  
  • Co-ordinate Bonding  
5 Chemical Thermodynamics
  • Introduction of Thermodynamics  
  • Thermodynamic Terms  
    • The System and the Surroundings
    • Types of the system
    1. Open System
    2. Closed system
    3. Isolated System
    4. Homogeneous system
    5. Heterogeneous system
    6. Macroscopic system
    • Macroscopic properties of the system
    1. Intensive properties
    2. Extensive properties
  • The State of the System  
    • The state of a system
    • State variables or state functions or thermodynamic parameters
    • State function: Initial and final states of the system
    • Path functions
    • Thermodynamic equilibrium and its types
    1. Chemical equilibrium
    2. Mechanical equilibrium
    3. Thermal equilibrium
    • Thermodynamic process and its types
    1. Isothermal process
    2. Adiabatic process
    3. Isobaric process
    4. Isochoric process
    5. Cyclic process
    6. Reversible process
    7. Irreversible process
    • Difference between reversible and irreversible process
  • The Internal Energy as a State Function - Work  
  • The Internal Energy as a State Function - Heat  
  • The Internal Energy as a State Function - the General Case  
    • First law of Thermodynamics
  • Thermodynamics Applications  
    • Work  
      • Pressure-volume work, reversible processes, irreversible processes
      • Isothermal and free expansion of an ideal gas
    • Enthalpy, H - a Useful New State Function  
    • Enthalpy, H - Extensive and Intensive Properties  
    • Enthalpy, H - Heat Capacity  
    • Enthalpy, H - The Relationship Between Cp and Cv for an Ideal Gas  
  • Measurement of ∆U and ∆H Calorimetry - ∆U Measurements  
  • Measurement of ∆U and ∆H Calorimetry - ∆H Measurements  
  • Enthalpy Change, ∆_rH of a Reaction - Reaction Enthalpy  
    • Standard Enthalpy of Reactions  
    • Enthalpy Changes During Phase Transformations  
      • Enthalpy of fusion
      • Enthalpy of vaporization
      • Enthalpy of sublimation
    • Standard Enthalpy of Formation  
    • Thermochemical Equations  
      • Heat of combustion
      • Molar heat capacities
      • Relation between Cp and Cv for an ideal gas
  • Chemical Thermodynamics and Energetic  
  • Enthalpies for Different Types of Reactions  
    • Standard Enthalpy of Combustion  
    • Enthalpy of Atomization  
    • Bond Enthalpy  
      • Bond dissociation enthalpy
      • Diatomic Molecules
      • Polyatomic Molecules
      • Mean bond enthalpy of C - H bond
    • Lattice Enthalpy  
      • Born-Haber Cycle
      • Enthalpy of ionization
    • Enthalpy of Solution  
    • Enthalpy of Dilution  
  • Spontaneity  
    • Is Decrease in Enthalpy a Criterion for Spontaneity  
    • Entropy and Spontaneity  
    • Gibbs Energy and Spontaneity  
    • Entropy and Second Law of Thermodynamics  
    • Absolute Entropy and Third Law of Thermodynamics  
  • Gibbs Energy Change and Equilibrium  
    • Relation between standard Gibbs energy change and equilibrium constant
  • Laws of Thermochemistry  
  • Basic Fundamentals of Thermodynamics  
7 Equilibrium
  • Concept of Equilibrium  
    • Equilibrium
    • Equilibrium state
    • Equilibrium mixture
    • Dynamic equilibrium
    • Chemical equilibrium
    • Ionic equilibrium
  • Equilibrium in Physical Processes  
    1. Liquid - Vapour equilibrium 
    2. Solid - liquid equilibrium
    3. Solid - vapour equilibrium
    • Solid-liquid Equilibrium  
    • Liquid-vapour Equilibrium  
    • Solid - Vapour Equilibrium  
    • Equilibrium Involving Dissolution of Solid in Liquids  
    • Equilibrium Involving Dissolution of Gases in Liquids  
      • Henry's law
    • General Characteristics of Equilibria Involving Physical Processes  
  • Equilibrium in Chemical Processes - Dynamic Equilibrium  
  • Law of Chemical Equilibrium and Equilibrium Constant  
    • Law of mass action
    • Law of chemical equilibrium
    • Characteristics of the equilibrium constant
    • Effect of temperature on equilibrium constant
    • Types of equilibrium constant
    • Relation between Kp and Kc
    • Unit of equilibrium constant
  • Homogeneous Equlibria  
    • Equilibrium Constant in Gaseous Systems
    • Equilibrium Constant in Gaseous Systems  
  • Heterogeneous Equlibria  
    • Equilibrium constant for heterogeneous equilibria
  • Applications of Equilibrium Constants  
    • Prediction of the direction of the reaction
    • To know the extent of reaction
    • To calculate equilibrium concentrations
    • Link between chemical equilibrium and chemical kinetics
    • Predicting the Extent of a Reaction  
    • Predicting the Direction of the Reaction  
    • Calculating Equilibrium Concentrations  
  • Relationship Between Equilibrium Constant K, Reaction Quotient Q and Gibbs Energy G  
    • Relationship between equilibrium constant, reaction quotient and change in Gibbs energy
  • Factors affecting equilibrium: Le Chatelier’s principle  
    • Application of Le-Chatelier's principle
    1. Applications to the chemical equilibrium
    2. Applications to the physical equilibrium
      a) Melting of ice (Ice-water system)
      b) Melting of sulphur
      c) Boiling of water (water-water vapour system)
      d) Solubility of salts
    • Change of Concentration  
      • Effect of change in concentration
    • Change of Pressure  
      • Effect of change in pressure
    • Addition of Inert Gas  
      • Effect of addition of inert gas
      1. Addition of an inert gas at constant volume
      2. Addition of an inert gas at constant pressure
    • Change of Temperature  
      • Effect of change in temperature
    • Effect of Catalyst  
  • Ionic Equilibrium in Solution  
    • Ionic equilibrium
    • Water-soluble compounds
    • Degree of ionization
    • Factors affecting degree of ionization
    • Weak and strong electrolytes
  • Concept of Acid, Base, and Salt  
    • Introduction
    • Acid
    • Base
    • Salt
  • Acids  
    • Definition: Acid
    • Arrhenius, Bronsted-lowry and Lewis Concept of Acids and Bases  
      • Arrhenius Concept of Acids and Bases
      • The Brönsted-Lowry Acids and Bases
      • Lewis Acids and Bases
  • Concept of Ionization of Acids and Bases  
  • Ionization of Acids and Bases  
    • The Ionization Constant of Water and Its Ionic Product  
      • Ionic product of water (Kw)
      • Value of Kw
    • Ionization Constants of Weak Acids  
      • Degree of ionization
    • Ionization of Weak Bases  
    • Relation Between Ka and Kb  
    • Di- and Polybasic Acids and Di- and Polyacidic Bases  
      • Ionization of polybasic acids
    • Factors Affecting Acid Strength  
    • Common Ion Effect in the Ionization of Acids and Bases  
    • Hydrolysis of Salts and the Ph of Their Solutions  
      • Hydrolysis of salt
      • Hydrolysis constant
      • Degree of hydrolysis (h)
      • Types of salts and their hydrolysis
  • Buffer Solutions  
  • Concept of Solubility Equilibria of Sparingly Soluble Salts  
    • Solubility Product Constant
    • Comparison of solubility product and ionic product
    • Different expressions for solubility product
    • Common Ion Effect on Solubility of Ionic Salts
    • Applications of solubility product
    • Common ion effect
    • Solution of weak acid and its salt
    • Solution of weak base and its salt
    • Common ion effect and solubility of a sparingly soluble salt
    • Applications of common ion effect
8 Redox Reactions and Electrochemistry
10 Surface Chemistry
11 Classification of Elements and Periodicity in Properties
12 General Principles and Processes of Isolation of Metals
13 Hydrogen
  • Position of Hydrogen in the Periodic Table  
    • Hydrogen
    • Position of hydrogen in the periodic table
  • Hydrogen  
    • Occurrence
    • Position of hydrogen in the periodic table
    • Isotopes of Hydrogen
    • Preparation of dihydrogen
    • Properties of dihydrogen
    • Uses of dihydrogen
  • Dihydrogen  
    • Occurrence of dihydrogen
    • Isotopes of Hydrogen
    • Physical constants of H2, D2, and T2
  • Preparation of Dihydrogen  
    • Preparation of Dihydrogen
    • By the action of water with metals
    • By the action of water on alkali and alkaline earth metal hydrides
    • By the reaction of metals like Zn, Sn, and Al with alkalies (NaOH or KOH)
    • By the action of metals with acids
    • By the electrolysis of acidified water
    • Laboratory method
    • Preparation of pure hydrogen
    • Commercial Production of Dihydrogen
      1) From hydrocarbon or coal
      2) Bosch process
      3) Lane's process
      4) By electrolysis of water
  • Properties and Uses of Dihydrogen  
    • Physical Properties
    • Physical constants of atomic and molecular properties
    • Chemical Properties
    1. Reaction with metals
    2. Reaction with non-metals
    3. Reaction with metal ions and metal oxides
    4. Reaction with organic compounds
    • Uses of Dihydrogen
  • Hydrides  
    • Hydrides
    • Classification of hydrides
    1. Saline or ionic hydrides
    2. Molecular or covalent hydrides
      a. Electron-rich molecular hydrides
      b. Electron-precise molecular hydrides
      c. Electron-deficient molecular hydrides
    3. Metallic or non-stoichiometric (or interstitial) hydrides
    • Ionic or Saline Hydrides  
    • Covalent or Molecular Hydride  
    • Metallic or Non-stoichiometric (or Interstitial) Hydrides  
  • Physical Properties of Water  
    • Physical Properties of Water:
    1. Nature
    2. Boiling point
    3. The freezing point of water or melting point of ice
    4. Density
    5. Anomalous expansion of water
    6. Latent heat of fusion of ice
    7. Latent heat of vaporization of water
    8. Specific heat capacity
  • Water  
    • Structure of Water  
    • Structure of Ice  
    • Temporary Hardness of Water  
      • Boiling
      • Clark's method
    • Permanent Hardness of Water  

      Treatment with washing soda (sodium carbonate), Calgon’s method, Ion-exchange method, Synthetic resins method

  • Chemical Properties of Water  
    • Chemical properties
    1. Dissociation of water
    2. Amphoteric nature
    3. Oxidising and reducing nature
    4. Hydrolytic reactions
    5. Formation of hydrates with metal salts
  • Classification of water: Soft and Hard Water  
    • Soft and Hard water
    • Types of Hard water
    1. Temporary Hardness
    2. Permanent Hardness
  • Hydrogen Peroxide  
  • Preparation of Hydrogen Peroxide  
    • Hydrogen peroxide (H2O2)
    • Preparation of hydrogen peroxide (H2O2)
    1. Merck's. process (Laboratory method)
    2. By the action of sulphuric acid or phosphoric acid on hydrated barium peroxide BaO2.8H2O
    3. Industrial method
    4. By redox process
    • Preparation of Deuterium
    • Electrolysis of heavy water
    • Preparation of Tritium
  • Physical Properties of Hydrogen Peroxide  
  • Structure of Hydrogen Peroxide  
  • Chemical Properties of Hydrogen Peroxide  
    • Chemical properties of H2O2
    1. Decomposition
    2. Oxidizing and reducing nature
    3. Oxidizing character
    4. Reducing character
    5. Bleaching action
    6. Storage of H2O2
  • Storage of Hydrogen Peroxide  
  • Uses of Hydrogen Peroxide  
  • Heavy Water  
    • Heavy water (D2O)
    • Preparation
    • Properties of heavy water
    • Reactions
    • Uses of heavy water
  • Dihydrogen as a Fuel  
  • Hydrogen as a Fuel  
14 S-block Elements (Alkali and Alkaline Earth Metals)
  • Group 1 Elements - Alkali Metals  
    • Electronic configuration of group 1 elements
    • Occurrence of group 1 elements
    • Atomic and ionic radii of group 1 elements
    • Ionization Enthalpy
    • Electropositive character
    • Electronegativity
    • Hydration Enthalpy
    • Anomalous properties
    • Physical properties of group 1 elements
    1. Nature and appearance
    2. Density
    3. Conductivity
    4. Melting and boiling points
    5. Photoelectric effect
    6. Characteristic flame colour
    7. Atomic and physical properties of group 1 elements
    • Chemical Properties - Reactivity towards air, water, dihydrogen, halogens, Reducing nature, Solutions in liquid ammonia
    • Uses of alkali metals: lithium, sodium, potassium
  • General Characteristics of the Compounds of the Alkali Metals  
    • Oxides and hydroxides
    • Halides
    • Salts of Oxo-Acids
  • Anomalous Properties of Lithium  
    • Points of Difference between Lithium and other Alkali Metals
    • Anomalous behaviour of lithium
    • Lithium differs from other alkali metals
    • Diagonal relationship of Li with Mg
    • Similarities between Li and Mg
  • Some Important Compounds of Sodium  
    • Sodium Carbonate (Washing Soda), Na2CO10H2O
    • Sodium Chloride, NaCl
    • Sodium Hydroxide (Caustic Soda), NaOH
    • Sodium Hydrogencarbonate (Baking Soda), NaHCO3
  • Group 2 Elements - Alkaline Earth Metals  
    • General characteristics of alkaline earth metals
    • Electronic configuration of group 2 elements
    • Occurrence of group 2 elements
    • Atomic and ionic radii of group 2 elements
    • Ionization enthalpy of group 2 elements
    • Electropositive character
    • Electronegativity
    • Hydration enthalpy
    • Physical properties of group 2 elements
    1. Nature and appearance
    2. Density
    3. Conductivity
    4. Melting and boiling points
    5. Characteristic flame colour
    6. Atomic and physical properties of group 2 elements
    • Chemical Properties - Reactivity towards air and water, halogens, hydrogen, Reducing nature, Covalent and ionic character, Solubility.
    • Distinctive behavior of beryllium 
    • Solutions in liquid ammonia
    • Reducing nature
    • Reactivity towards acids
    • Uses: beryllium, magnesium, calcium, barium, radium
  • General Characteristics of the Compounds of the Alkaline Earth Metals  
    • General characteristics of some compounds of the alkaline earth metals
    1. Oxides and Hydroxides
    2. Halides - Structure of BeCl2
    3. Salts of Oxoacids
    • Carbonates of group 2 elements
    • Sulphates of group 2 elements
    • Nitrates of group 2 elements
  • Anomalous Behaviour of Beryllium  
    • Anomalous behaviour of beryllium
    • Be differs from other alkaline earth metals
    • Diagonal Relationship between Beryllium and Aluminium
    • Reasons for diagonal relationship
    • Similarities between Be and Al
  • Some Important Compounds of Calcium  
    • Calcium oxide or Quick Lime (CaO)
    • Uses of lime
    • Calcium Hydroxide (Slaked lime), Ca(OH)2
    • Uses of slaked lime
    • Calcium Carbonate (CaCO3) or limestone
    • Uses of limestone
    • Calcium Sulphate (Plaster of Paris), CaSO4.½ H2O
    • Uses of plaster of Paris
    • Uses of cement
  • Biological Importance of Magnesium and Calcium  
    • Role of Mg in biological system
    • Role of Ca in biological system
  • Biological Importance of Sodium and Potassium  
15 P-block Elements
  • Introduction to p-block Elements  
    • General introduction of p-block elements
    • Electronic configuration of p-block elements
    • General characteristics of p-block elements
    1. Oxidation states
    2. Metallic and nonmetallic character
    3. Variation in physical properties
    4. Difference in behaviour of first element of each group
  • Group 13 Elements - The Boron Family  
    • Occurrence,
    • Electronic Configuration,
    • Atomic and Ionic Radii,
    • Ionisation Enthalpy,
    • Electropositivity or metallic character,
    • Electronegativity,
    • Atomic and physical properties of group 13 elements,
    • Physical Properties and Chemical Properties,
    • Trends in chemical reactivity: Oxidation state.
    • Boron  
      • Preparation, properties, and uses of boron
    • Aluminum  
      • Preparation, properties, and uses of aluminum
  • Some Important Compounds of Boron  
    • Structure, properties, and uses of some important compounds of Boron
      (1) Borax or sodium tetraborate decahydrate (Na2B4O 7.10H2O) or Na2[B4O5(OH)4].8H2O
      (2) Boric acid or orthoboric acid (H3BO3)
      (3) Diborane (B2H6)
      (4) Boron trifluoride
  • Some Important Compounds of Aluminium  
    • Structure, properties, and uses of some important compounds of Aluminum:
      (1) Aluminum chloride
      (2) Alums
  • Group 14 Elements - The Carbon Family  
    • Electronic Configuration
    • Occurrence
    • Atomic and ionic radii
    • Covalent Radius
    • Ionization Enthalpy
    • Metallic character
    • Electronegativity
    • Physical Properties and Chemical Properties
    • Trends in chemical reactivity: oxidation states
  • Important Trends and Anomalous Behaviour of Carbon  
    • The tendency for catenation
  • Allotropes of Carbon > Graphite  
    • Graphite
    • Experiment
    • Uses of Graphite
  • Allotropes of Carbon > Fullerene  
    • Fullerene
    • Uses of Fullerene
  • Allotropes of Carbon > Diamond  
    • Crystalline Forms
    • Diamond
    • Uses of Diamond
  • Some Important Compounds of Carbon and Silicon - Carbon Monoxide  
  • Some Important Compounds of Carbon and Silicon - Carbon Dioxide  
  • Some Important Compounds of Carbon and Silicon - Silicon Dioxide  
  • Some Important Compounds of Carbon and Silicon - Silicones  
  • Some Important Compounds of Carbon and Silicon - Silicates  
  • Some Important Compounds of Carbon and Silicon - Zeolites  
  • Concept of Group 15 Elements  
    • Occurrence
    • Electronic Configuration
    • Atomic and Ionic Radii
    • Ionisation Enthalpy
    • Electronegativity
    • Physical Properties and Chemical Properties
  • p-Block elements of Group 15 Elements  
    • Ammonia  
      • Preparation, Properties, Uses
    • Oxides of Nitrogen  
      • Oxides of Nitrogen
      • Oxoacids of nitrogen
      • Structures of Oxides of Nitrogen
    • Phosphorus Halides  
      • Phosphorus Trichloride - Preparation, Properties, Uses
      • Phosphorus Pentachloride - Preparation, Properties, Uses
  • Concept of Group 16 Elements  

    Occurrence, Electronic Configuration, Atomic and Ionic Radii, Ionisation Enthalpy, Electron Gain Enthalpy, Electronegativity, Physical Properties and Chemical Properties (Oxidation states and trends in chemical reactivity and Anomalous behaviour of oxygen)

  • P - Block Group 16 Elements  
    • Ozone  
      • Preparation, properties, structures, and uses
  • Concept of Group 17 Elements  

    Occurrence, Electronic Configuration, Atomic and Ionic Radii, Ionisation Enthalpy, Electron Gain Enthalpy, Electronegativity, Physical Properties and Chemical Properties (Oxidation states and trends in chemical reactivity and Anomalous behaviour of fluorine)

  • Compounds of Halogens  
  • P - Block Group 17 Elements  
  • Trends in the Acidic Nature of Hydrogen Halides  
  • P - Block Group 18 Elements  
18 Environmental Chemistry
  • Atmospheric Pollution  
    • Tropospheric Pollution - Gaseous Air Pollutants  
      • Air pollution
      • Types of Air pollution
        1) Tropospheric pollution
        2) Stratospheric pollution
      • Sources of air pollution
      • Types of air pollutants
        1) Primary air pollutants
        2) Secondary air pollutants
      • Major atmospheric pollutants
        1) Oxides of carbon: Carbon monoxide (CO), Carbon dioxide (CO2), Sulphur dioxide (SO2), Nitrogen oxides (NOx), Hydrocarbons
      • Global Warming and Greenhouse Effect
      • Acid rain
    • Tropospheric Pollution - Particulate Pollutants  
      • Particulate pollutants
      • Source
      1. Smoke
      2. Dust
      3. Fumes
      4. Mists
      5. Effects of air pollution
      • Smog
      • Effects of photochemical smog
      • Acid rain
      • Ozone
      • Greenhouse effect and global warming
    • Stratospheric Pollution  
      • Stratospheric Pollution
      • Formation and Breakdown of Ozone
      • The Ozone Hole
      • Effects of Depletion of the Ozone Layer
  • International Standards for Drinking Water  
    • Fluoride, Lead, Sulphate, Nitrate, Other metals
  • Environmental Issues  
  • Industrial Waste  
    • Types of industrial waste
    1. Biodegradable wastes
    2. Non-biodegradable wastes
  • Strategies to Control Environmental Pollution  
    • Strategy to control environmental pollution
    1. Incineration
    2. Digestion
    3. Collection and disposal
    4. Sewage treatment
    5. Other strategies
  • Green Chemistry - Introduction  
  • Green Chemistry in Day-to-day Life  
    • Dry Cleaning of Clothes
    • Bleaching of Paper
    • Synthesis of Chemicals
    • ‘Green Solution’ to Clean Turbid Water
19 Purification and Characterisation of Organic Compounds
  • Introduction of Methods of Purification of Organic Compounds  
  • Purification of Solids  
  • Sublimation  
    • Introduction
    • Experiment
  • Methods of Separation  
    • Distillation Under Reduced Pressure (Vacuum Distillation)  
    • Steam Distillation  
  • Chromatography Method > Adsorption Chromatography  
  • Chromatography Method > Partition Chromatography  
    • Retention factor (Rf)
  • Qualitative Analysis of Organic Compounds - Detection of Carbon and Hydrogen  
  • Qualitative Analysis of Organic Compounds - Detection of Other Elements  
    • Test for Nitrogen
    • Test for Sulphur
    • Test for Halogens
    • Test for Phosphorus
  • Quantitative Analysis of Carbon and Hydrogen  
  • Quantitative Analysis of Nitrogen  
    • Dumas method
    • Kjeldahl’s method
  • Quantitative Analysis of Halogens  
    • Carius method
  • Quantitative Analysis of Sulphur  
  • Quantitative Analysis of Phosphorus  
  • Quantitative Analysis of Oxygen  
  • Empirical Formula and Molecular Formula  
    • Determination of Empirical Formula from Elemental Analysis Data
    • Calculation of Molecular Formula from Empirical Formula
20 Some Basic Principles of Organic Chemistry
  • Tetravalence of Carbon - Shapes of Organic Compounds  
    • Tetravalency of carbon
    • The Shapes of Carbon Compounds
    • Some Characteristic Features of σ and π Bonds
  • Organic Compounds  
    • Definition: Organic Compounds
    • Key Points: Organic Compounds
    • Complete, Condensed and Bond-line Structural Formulas  
      • Representation of organic molecules (2-D)
      1. Lewis structure/ dot structure
      2. Dash formula/ structural formula
      3. Condensed structural formula
      4. Bond-line formula
    • Three-dimensional Representation of Organic Molecules  
      • Three-dimensional representation of organic compounds
      1. Wedge and dash formula
      2. Fischer projection (Cross) formula
      3. Newman projection formula
      4. Sawhorse or andiron or perspective formula
  • Classification of Organic Compounds  
    • Classification based on carbon skeleton
    • Classification based on functional group
    • Homologous Series
  • Nomenclature  
    • Definition: Nomenclature
    • Key Points: Nomenclature of Carbon Compounds
    • IUPAC Nomenclature of Alkanes  
      • Rules for IUPAC nomenclature of saturated hydrocarbons (alkanes)
      • Rules for naming cyclic or alicyclic hydrocarbons
      • Rules for naming compounds containing double and triple bonds
      • Straight chain hydrocarbons
      • Branched-chain hydrocarbons,
      • Nomenclature of branched-chain alkanes
      • Cyclic Compounds
    • Nomenclature of Organic Compounds Having Functional Group(s)  
    • Nomenclature of Substituted Benzene Compounds  
  • Isomerism  
    • Definition: Isomers
  • Fundamental Concepts in Organic Reaction Mechanism  
    • Fission of a Covalent Bond  
      • Heterolytic cleavage
      • Homolytic cleavage
      • Free radicals
      • Carbocations, and carbanions
      • Stability of carbocations and free radicals
    • Nucleophiles and Electrophiles  
    • Electron Movement in Organic Reactions  
    • Electron Displacement Effects in Covalent Bonds  
      • Electronic displacement in covalent bond
      • Significance of electronic displacement
    • Inductive Effect  
      • Inductive effect
      • Types of inductive effect
      1. Negative inductive effect
      2. Positive inductive effect
    • Resonance Structure  
    • Resonance Effect  
      • Resonance or mesomerism
      • Features of resonating structures
      • Resonance effect or Mesomeric effect
      • Movement or flow of electrons
      • Types of resonance effect
      1. Positive Resonance Effect (+R effect)
      2. Negative Resonance Effect (- R effect)
    • Electromeric Effect (E Effect)  
      • Electromeric effect
      • Types of electromeric effect
      1. +E effect
      2. -E effect
      • Direction of the shift of electron pairs
    • Hyperconjugation  
      • Hyperconjugation
      • Hyperconjugation effect or Baker and Nathan effect
      • No-bond resonance
      • Structural requirements for hyperconjugation
      • Hyperconjugation and carbocation
    • Types of Organic Reactions and Mechanisms  
      • Substitution reactions
      • Addition reactions
      • Elimination reactions
      • Rearrangement reactions
      • Condensation reaction
      • Isomerisation reaction
21 Hydrocarbons
  • Classification of Hydrocarbons  
  • Alkanes - Introduction  
    • Alkanes (Paraffins)
    • General formula
    • Occurrence
    • Structure of alkanes
    • Classification
    • Uses of alkanes
  • Alkanes  
    • Definition: Alkanes
    • Nomenclature and Isomerism  
      • Nomenclature of alkanes
      • Common system
      • IUPAC system
      • IUPAC names of some straight-chain alkanes
      • IUPAC names of some alkyl groups
      • Common and IUPAC names of some alkanes
      • IUP AC naming of cycloalkanes
      • Isomerism of alkanes
    • Preparation of Alkanes from Unsaturated Hydrocarbons, Alkyl Halides and Carboxylic Acids  
      • Methods of preparation of alkanes
      • From unsaturated hydrocarbons (By catalytic hydrogenation of alkenes and alkynes)
      1. From alkenes
      2. From alkynes
      • From alkyl halides (Wurtz reaction)
      • From alkyl halides (Corey-House reaction)
      • Reduction of alkyl halides
      • By the use of Grignard reagent
      • Decarboxylation reaction
      • From carboxylic acids by electrolysis (Kolbe's electrolytic method)
      • Reduction of carboxylic acids
    • Conformations (Ethane)  
      • Conformations
      • Conformations of ethane: Eclipsed and Staggered conformation 
      • Representation: Sawhorse and Newman projections
      • Relative stabilities of the conformations of ethane
  • Mechanism of Halogenation of Alkane  
  • Physical Properties of Alkanes  
    • Physical properties of alkanes
    1. Nature
    2. Boiling point
    3. Melting point
    4. Solubility
    5. Density
  • Chemical Properties of Alkanes  
    • Chemical properties of alkanes
    1. Substitution reactions - Halogenation, Nitration, Sulphonation
    2. Combustion of alkanes (oxidation)
    3. Controlled oxidation
    4. Isomerisation
    5. Aromatization
    6. Reaction with steam
    7. Pyrolysis
  • Alkenes  
    • Definition: Alkenes
    • Structure of Double Bond (Ethene)  
      • Electronic structure of ethene or ethylene
    • Nomenclature  
      • Nomenclature of alkenes
      • Common names
      • IUPAC nomenclature
      • The common and IUPAC names of some alkenes
    • Preparation of Alkenes from Alkynes, Alkyl Halides, Vicinal Dihalides and Alcohols by Acidic Dehydration  
      • Methods of preparation of alkenes
      1. From alkyl halides (dehydrohalogenation reaction)
      2. From dihalogen derivatives (dehalogenation of vicinal dihalide)
      3. From alkynes (catalytic hydrogenation)
      4. From alcohols (dehydration reaction)
      5. From potassium salts of dicarboxylic acids (Kolbe's reaction)
  • Isomerism  
    • Definition: Isomers
  • Physical Properties of Alkenes  
    • Key Points: Physical Properties of Alkenes
  • Chemical Properties of Alkenes  
    • Key Points: Chemical Properties of Alkenes
  • Alkynes  
    • Definition: Alkynes
    • Nomenclature and Isomerism  
      • Nomenclature of alkynes
      • Common system
      • Derived system
      • IUPAC system
      • Common names and IUPAC names of some of the alkynes
      • Isomerism in alkynes
      • Chain isomerism
      • Position isomerism
      • Functional isomerism
      • Ring chain isomerism
    • Structure of Triple Bond  
    • Preparation of Alkynes from Calcium Carbide and Vicinal Dihalides  
      • Methods of preparation of alkynes
      1. Action of water on calcium carbide: Industrial preparation of acetylene
      2. By dehydrohalogenation of vicinal dihalides or geminal dihalides: From vicinal dihalide, From geminal dihalide, Double dehydrohalogenation
      3. By the action of zinc on tetrahalogen derivatives of alkanes (dehalogenation)
      4. Kolbe's electrolysis reaction
      5. By dehalogenation of haloform
      6. Berthelot's synthesis
      7. Synthesis of higher alkynes
  • Physical Properties of Alkynes  
    • Physical properties of alkynes
    1. Nature
    2. Solubility
    3. Melting point and Boiling point
  • Chemical Properties of Alkynes  
    • Acidic character of alkyne
    • Formation of alkali metal ethynides (acetylides)
    • Formation of heavy metal ethynides (acetylides)
    • Formation of alkynyl Grignard reagents
    • Addition reactions
    • Addition of dihydrogen
    • Addition of hydrogen (catalytic hydrogenation or reduction of alkynes)
    • Addition of halogens (anti-addition): Action of chlorine, Action of bromine
    • Addition of halogen acids (hydrogen halides)
    • Addition of water (acid-catalyzed hydration of alkynes)
    • Oxidation reactions
    • Combustion
    • Oxidation with alkaline potassium permanganate (test for unsaturation)
    • Oxidative hydroboration
    • Ozonolysis reactions
    • Polymerization reactions: Linear and Cyclic polymerization
  • Aromatic Hydrocarbons  
    • Benzene
    • Structure of benzene
    • Aromatic character (Huckel Rule)
    • Preparation of aromatic compounds
    • Physical properties of benzene
    • Chemical properties of benzene
    • Directive influence of a functional group in monosubstituted benzene
    • Carcinogenicity and Toxicity
    • Nomenclature and Isomerism  
      • Nomenclature of Aromatic hydrocarbons: IUPAC nomenclature
      • Isomerism in Aromatic hydrocarbons
    • Structure of Benzene  
      • Benzene
      • Structure of benzene
      1. Molecular formula
      2. Cyclic structure
      3. Evidence for cyclic structure
      • Resonance and stability of benzene
    • Aromaticity (Huckel Rule)  
      • Aromaticity: 
      • Huckel rule and its applications
      • Antiaromaticity
    • Preparation of Benzene  
      • Preparation of Benzene
      1. From acetylene/ethyne (trimerization)
      2. Decarboxylation of aromatic compounds (Laboratory method)
      3. Reduction of phenol
    • Electrophilic Substitution Reactions  
      • Electrophilic substitution reactions
      1. Nitration
      2. Halogenation
      3. Sulphonation
      4. Friedel-Crafts alkylation reaction
      5. Friedel-Crafts acylation reaction
    • Mechanism of Electrophilic Substitution Reactions  
      • Mechanism of electrophilic substitution reactions
      1. Generation of the eletrophile
      2. Formation of carbocation intermediate
      3. Removal of proton from the carbocation intermediate
      • Addition reactions - Combustion
    • Directive Influence of a Functional Group in Monosubstituted Benzene  
      • Directive effect
      • Activity effects
      • Ortho, para, and meta directing groups
  • Physical Properties of Aromatic Hydrocarbons  
  • Chemical Properties of Aromatic Hydrocarbons  
  • Carcinogenicity and Toxicity  
22 Organic Compounds Containing Halogens
23 Organic Compounds Containing Oxygen
25 Polymers
26 Biomolecules
27 Chemistry in Everyday Life

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