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Properties of Dia, Para, and Ferromagnetic Substances

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Estimated time: 13 minutes
CISCE: Class 12

Introduction

All materials respond to an external magnetic field, but the nature and strength of this response vary. Based on their magnetic behaviour, substances are classified into three categories: diamagnetic, paramagnetic, and ferromagnetic.

Key Idea: This classification depends on whether a material's magnetic moment aligns against, weakly with, or strongly with an applied magnetic field.

CISCE: Class 12

Definition: Diamagnetic Substances

Diamagnetic substances are materials that are weakly magnetised in a direction opposite to the applied magnetic field and are weakly repelled by it.

CISCE: Class 12

Definition: Paramagnetic Substances

Paramagnetic substances are weakly magnetised in the same direction as the applied field and are weakly attracted toward regions of stronger field.

CISCE: Class 12

Definition: Ferromagnetic Substances

Ferromagnetic substances are strongly magnetised in the direction of the applied field and are strongly attracted by magnets, even retaining magnetism after the field is removed.

CISCE: Class 12

Diamagnetic Substances

It happens because:

  • All electrons in diamagnetic atoms are paired, so individual atomic magnetic moments cancel out.
  • On applying an external field, induced currents create a small magnetic moment opposing the field (Lenz's Law analogy).

Key properties

Property Behavior
Susceptibility (χm) Small and negative
Relative Permeability (μr) Slightly less than 1
Field Line Behaviour Field lines pushed away from the material
Temperature Dependence Independent of temperature
Behaviour in Non-Uniform Field Moves toward weaker field region

Examples

Bismuth, copper, gold, silver, water, and superconductors (perfect diamagnets, χm = −1).

CISCE: Class 12

Paramagnetic Substances

It happens because:

  • Atoms possess a permanent (but randomly oriented) magnetic dipole moment due to unpaired electrons.
  • On applying a field, dipoles partially align with it; thermal agitation prevents full alignment.

Key Properties

Property Behavior
Susceptibility (χm) Small and positive
Relative Permeability (μrμr​) Slightly greater than 1
Field Line Behaviour Field lines concentrate inside material
Temperature Dependence Inversely proportional to temperature (Curie's Law)
Behaviour in Non-Uniform Field Moves toward stronger field region

Curie's Law

  • χm = \[\frac {C}{T}\]

Where C = Curie constant, T = absolute temperature (Kelvin).

Examples: Aluminium, platinum, chromium, oxygen (O₂ gas), sodium.

CISCE: Class 12

Ferromagnetic Substances

It happens because:

  • Atoms form magnetic domains — regions where atomic dipoles are already aligned.
  • An external field causes domain growth/alignment, producing strong net magnetisation.

Key Properties

Property Behavior
Susceptibility (χm​) Large and positive
Relative Permeability (μr​) Very high (100s – 1000s)
Retentivity Retains magnetism after field removal
Hysteresis Exhibits B–H hysteresis loop
Temperature Dependence Follows Curie–Weiss Law above Curie point

Curie–Weiss Law

χm = \[\frac {C}{T−T_c}\] (T > Tc)

Where Tc​ = Curie temperature — the temperature above which a ferromagnet becomes paramagnetic.

Material Curie Temperature (°C)
Iron (Fe) 770
Nickel (Ni) 358
Cobalt (Co) 1120

Examples: Iron, cobalt, nickel, and their alloys (e.g., Alnico, steel).

CISCE: Class 12

Consolidated Comparison Table

Property Diamagnetic Paramagnetic Ferromagnetic
Magnetic Moment Origin None (induced) Permanent, unpaired electrons Domain alignment
Susceptibility Small, negative Small, positive Large, positive
Relative Permeability < 1 Slightly > 1 ≫ 1
Effect of Field Weak repulsion Weak attraction Strong attraction
Non-Uniform Field Motion Toward weaker field Toward stronger field Strongly toward stronger field
Temperature Effect No effect Curie's Law (∝ 1/T) Curie–Weiss Law above Tc
Retains Magnetism? No No Yes (until demagnetised)
Examples Bi, Cu, Au, H₂O Al, Pt, O₂ Fe, Co, Ni
CISCE: Class 12

Real-Life Examples

  • Analogy for Ferromagnetism: Think of domains as soldiers in formation — normally facing random directions, but a "command" (external field) makes them align and march together, staying aligned even after the command stops.
  • Analogy for Paramagnetism: Like compass needles scattered on a table — they turn to align with a nearby magnet but flop back randomly once it is removed.
  • Analogy for Diamagnetism: Like a crowd instinctively stepping back from a pushing force — a mild, automatic opposition, not a personal choice.
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