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Photoelectric Effect and Wave Theory of Light

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Estimated time: 6 minutes
CBSE: Class 12

Wave Nature of Light

By the end of the nineteenth century, the wave nature of light was well established.

The phenomena of interference, diffraction, and polarisation were explained in a natural and satisfactory way by the wave picture of light.

According to this picture, light is an electromagnetic wave consisting of electric and magnetic fields with a continuous distribution of energy over the region of space over which the wave is extended.

CBSE: Class 12

Predictions of Wave Theory

The given material examines whether the wave picture of light can explain the observations of photoelectric emission.

According to the wave picture, free electrons at the surface of a metal continuously absorb radiant energy when radiation falls on the surface.

According to the wave theory of light:

  • The free electrons at the metal surface should absorb energy continuously from the incident radiation.
  • Greater radiation intensity means greater amplitudes of the electric and magnetic fields.
  • Therefore, greater intensity should lead to greater energy absorbed by each electron.
  • As a result, the maximum kinetic energy of photoelectrons should increase with increasing intensity.
  • A sufficiently intense beam of radiation, given enough time, should supply enough energy to electrons to escape from the metal surface, whatever the frequency.
  • Hence, according to wave theory, a threshold frequency should not exist.
CBSE: Class 12

Contradiction with Observations

These expectations of the wave theory directly contradict the observed features of photoelectric emission referred to in the source.

The source particularly points out that the wave theory fails in the following way:

  • It predicts an increase in maximum kinetic energy with increasing intensity.
  • It suggests that photoelectric emission should be possible even for low-frequency radiation, provided the beam is sufficiently intense and acts for a sufficient time.
  • It therefore does not support the existence of a threshold frequency.
CBSE: Class 12

Problem of Continuous Absorption

The source further states that, in the wave picture, the absorption of energy by an electron takes place continuously over the entire wavefront of the radiation.

Since a large number of electrons absorb energy, the energy absorbed by each electron per unit time becomes very small.

Explicit calculations estimate that a single electron may take hours or more to gain enough energy to overcome the work function and escape from the metal.

CBSE: Class 12

Instantaneous Emission

This conclusion is in striking contrast to the observation that photoelectric emission is instantaneous.

Thus, the wave picture cannot explain the immediate emission of electrons from the metal surface.

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