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Heat, Internal Energy and Work

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Estimated time: 7 minutes
CBSE: Class 12
Maharashtra State Board: Class 11

Definition: Heat

The energy transfer due to temperature difference between a system and its surroundings is called heat.

OR

The energy that exchanges between a system and its environment because of the temperature difference between them is called heat.

  • SI unit: joule (J); CGS unit: calorie

CBSE: Class 12
Maharashtra State Board: Class 11

Definition: Internal Energy

The total energy possessed by any system due to molecular motion and molecular configuration is called internal energy.

OR

The energy possessed by a system due to molecular motion and molecular configuration is called internal energy.

U = Uk + Up

where Uk​ = internal kinetic energy (due to molecular motion) and Up​ = internal potential energy (due to molecular configuration).

CBSE: Class 12

Definition: Work

The energy transferred to or from a system when an external force acts on the system's boundary, causing it to move, is called work.

CBSE: Class 12

Formula: Change in Internal Energy

ΔU = \[\frac {3}{2}\]​nRΔT

CBSE: Class 12

Formula: Heat Absorbed

ΔQ = ms(T2​ − T1​)

CBSE: Class 12

Key Points: P-V Diagrams

  • Isothermal → P-V diagram: Hyperbolic curve (inverse relation); T-V: horizontal line; T-P: vertical line.
  • Adiabatic → P-V diagram: Steeper curve than isothermal; T-V: exponential decay/growth; P-T: exponential decay/growth.
  • Work done = area under the P-V curve.
  • Adiabatic curve is steeper because γ > 1 (slope = −γP/V vs −P/V for isothermal).

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