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Degrees of Freedom

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Estimated time: 5 minutes
CBSE: Class 12
Maharashtra State Board: Class 11

Definition: Degrees of Freedom

The total number of coordinates or independent quantities required to describe the position and configuration of a system completely is called degrees of freedom (dof).

OR

The total number of independent modes (translational, rotational, vibrational) in which a system can possess energy — i.e., the number of independent ways in which a molecule or atom can exhibit motion — is called the degree of freedom.

CBSE: Class 12
Maharashtra State Board: Class 11

Formula: Degrees of Freedom

f = 3A − B

where:

  • A = number of atoms in the molecule
  • B = number of bonds between atoms
CBSE: Class 12

Definition: Translational Degree of Freedom

The maximum three degrees of freedom corresponding to translational motion is called translational degree of freedom.

CBSE: Class 12

Definition: Rotational Degree of Freedom

The number of degrees of freedom that depends on the structure of the molecule, corresponding to rotational motion, is called rotational degree of freedom.

CBSE: Class 12

Definition: Vibrational Degree of Freedom

The degree of freedom exhibited at high temperatures corresponding to vibrational motion is called vibrational degree of freedom.

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