Advertisements
Advertisements
प्रश्न
Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):

(i) 
(ii) 
(iii) 
(iv) 
Advertisements
उत्तर
(i) 
(ii) 
Explanation:
The given compound is a planar molecule with sp2 hybridized carbon. Carbon atoms are attacked by nucleophiles. If the nucleophile approaches from the front, the (i) and (ii) molecules shift to the front and back positions, respectively and the carbon becomes tetrahedral. Another alternative is that (i) and (ii) molecules will be located above and below the plane, respectively. As a result, the choices (iii) and (iv) aren't represented as planar molecules.
APPEARS IN
संबंधित प्रश्न
Arrange the following compound in increasing order of its reactivity in nucleophilic addition reactions.
Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.
Hint: Consider steric effect and electronic effect.
What is meant by the following term? Give an example of the reaction in the following case.
Oxime
How are the following compounds prepared?
acetophenone from benzene
Write balanced chemical equations for action of ammonia on - acetone
Write balanced chemical equations for action of ammonia on - acetone
What are amines?
How will you convert sodium acetate to methane?
Acetone, Acetaldehyde, Benzaldehyde, Acetophenone – reactivity towards addition of HCN.
Reaction of aqueous sodium hydroxide on chlorobenzene gives which of the following products?
Which one of the following gives only one monochloro derivative?
The most stable reagent for the conversion of R – CH2OH → RCHO is
What is the action of sodium hypoiodite on acetone?

The product "P" in the above reaction is:
Out of p-tolualdehyde and p-nitrobenzaldehyde, which one is more reactive towards nucleophilic addition reactions, why?
Draw structure of the following derivative.
Acetaldehydedimethylacetal
Draw the structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative:
Acetaldehydedimethylacetal
Draw the structure of the following derivative.
Acetaldehydedimethylacetal
