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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Write Balanced Chemical Equations for Action of Ammonia on - Acetaldehyde

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प्रश्न

Write balanced chemical equations for action of ammonia on - acetaldehyde

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उत्तर

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2013-2014 (October)

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व्हिडिओ ट्यूटोरियलVIEW ALL [1]

संबंधित प्रश्‍न

Draw the structure of the semicarbazone of ethanal.


Write the products formed when CH3CHO reacts with the following reagents : HCN

 


Arrange the following compound in increasing order of its reactivity in nucleophilic addition reactions.

Ethanal, Propanal, Propanone, Butanone.

Hint: Consider steric effect and electronic effect.


Predict the product of the following reaction:


What is meant by the following term? Give an example of the reaction in the following case.

Cyanohydrin


What is meant by the following term? Give an example of the reaction in the following case.

Imine


What is meant by the following term? Give an example of the reaction in the following case.

Schiff’s base


Give plausible explanation for the following:

There are two −NH2 groups in semicarbazide. However, only one is involved in the formation of semicarbazones.


How will you convert sodium acetate to methane?


 Acetone, Acetaldehyde, Benzaldehyde, Acetophenone – reactivity towards addition of HCN. 


How will you convert benzoic acid to m-bromobenzoic acid?


Write a test to differentiate between pentan-2-one and pentan-3-one.


Identify the compounds A, B and C in the following reaction.

\[\ce{CH3 - Br ->[Mg/ether] (A) ->[(i) CO][(ii) Water] (B) ->[CH3OH/H+][Δ] (C)}\]


Which one of the following gives only one monochloro derivative?


Arrange the following in the increasing order of their property indicated:

Ethanal, Propanone, Propanal, Butanone (reactivity towards nucleophilic addition)


The product "P" in the above reaction is:


The product of following reaction is

\[\ce{CH3 - CH = CH - CH2 - CHO ->[i) LiAlH4][ii) H3O+]}\] ______?


The following questions are case-based questions. Read the passage carefully and answer the questions that follow:

The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols.

Answer the following:

(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)

(b) Why carboxylic acid is a stronger acid than phenol? (1)

(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)

CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\],  \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]

(ii) Write a chemical test to distinguish between propanal and propanone. (1)

OR

(c) Write the main product in the following: (2)

(i)
(ii)

Aldehydes and ketones react with hydroxylamine to form ______.


Draw structures of the given derivatives.

The ethylene ketal of hexan-3-one


Why dissociation of HCN is suppressed by the addition of HCL?


Draw structures of the following derivative.

The ethylene ketal of hexan-3-one


Draw the structure of the following derivative.

Acetaldehydedimethylacetal


Draw the structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw structures of the following derivatives.

Acetaldehydedimethylacetal


Draw structures of the given derivatives.

The ethylene ketal of hexan-3-one


Draw the structure of the given derivative.

The ethylene ketal of hexan-3-one


Complete the following reaction:

[C] is __________.


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