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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

What is meant by the following term? Give an example of the reaction in the following case. Cyanohydrin

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प्रश्न

What is meant by the following term? Give an example of the reaction in the following case.

Cyanohydrin

रासायनिक समीकरणे/रचना
लघु उत्तर
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उत्तर

Aldehydes and ketones react with hydrogen cyanide (HCN) to yield cyanohydrins. This reaction occurs very slowly with pure HCN. Therefore, it is catalysed by a base and the generated cyanide ion (CN) being a stronger nucleophile readily adds to carbonyl compounds to yield corresponding cyanohydrin.

\[\ce{HCN + O\overset{-}{H} <=> {_{\bullet}^{\bullet}}\overset{-}{C}N + H2O}\]

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पाठ 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ २५५]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.1 (i) | पृष्ठ २५५

संबंधित प्रश्‍न

Predict the products of the following reactions:

 


Write the structures of the main products when acetone (CH3 − CO − CH3) reacts with the following reagent :

H2N − NHCONH2/H+


Arrange the following compound in increasing order of its reactivity in nucleophilic addition reactions.

Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.

Hint: Consider steric effect and electronic effect.


What is meant by the following term? Give an example of the reaction in the following case.

2, 4-DNP-derivative


How will you bring about the following conversion in not more than two steps?

Bromobenzene to 1-Phenylethanol


Complete the synthesis by giving missing starting material, reagent or product.

\[\ce{C6H5CHO ->[H2NCONHNH2]}\]


What is the action of the following reagents on ethanoic acid?

1) `LiAlH_4"/"H_3O^+`

2) `PCl_3 , "heat"`

3) `P_2O_5, "heat"`


 Acetone, Acetaldehyde, Benzaldehyde, Acetophenone – reactivity towards addition of HCN. 


Write a test to differentiate between pentan-2-one and pentan-3-one.


Which one of the following gives only one monochloro derivative?


Which of the following has the most acidic hydrogen?


The product "P" in the above reaction is:


The increasing order of the following compounds towards HCN addition is:

(i)
(ii)
(iii)
(iv)

Write the structure of the product formed when acetone reacts with 2, 4 DNP reagent.


Draw structures of the following derivative.

The ethylene ketal of hexan-3-one


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one


Which of the following will not be formed when calcium formate is distilled with calcium acetate?


The major product of the following reaction is:


Complete the following reaction:

[C] is __________.


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