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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

What is meant by the following term? Give an example of the reaction in the following case. Cyanohydrin - Chemistry

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प्रश्न

What is meant by the following term? Give an example of the reaction in the following case.

Cyanohydrin

रासायनिक समीकरणे/रचना
लघु उत्तर
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उत्तर

Aldehydes and ketones react with hydrogen cyanide (HCN) to yield cyanohydrins. This reaction occurs very slowly with pure HCN. Therefore, it is catalysed by a base and the generated cyanide ion (CN) being a stronger nucleophile readily adds to carbonyl compounds to yield corresponding cyanohydrin.

\[\ce{HCN + O\overset{-}{H} <=> {_{\bullet}^{\bullet}}\overset{-}{C}N + H2O}\]

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  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ २५५]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.1 (i) | पृष्ठ २५५

संबंधित प्रश्‍न

Arrange the following in the increasing order of their reactivity towards nucleophilic addition reaction:

C6H5COCH3, CH3-CHO, CH3COCH3


Predict the products of the following reactions:

 


Write the products formed when CH3CHO reacts with the following reagents : HCN

 


What is meant by the following term? Give an example of the reaction in the following case.

2, 4-DNP-derivative


Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.

Excess ethanol and acid


Arrange the following compounds in increasing order of their property as indicated:

Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards HCN)


Complete the synthesis by giving missing starting material, reagent or product.

\[\ce{C6H5CHO ->[H2NCONHNH2]}\]


How are the following compounds prepared?

acetophenone from benzene


 Acetone, Acetaldehyde, Benzaldehyde, Acetophenone – reactivity towards addition of HCN. 


Carboxylic acids contain carbonyl group but do not show the nucleophilic addition reaction like aldehydes or ketones. Why?


Reaction of aqueous sodium hydroxide on chlorobenzene gives which of the following products?


What happens when ethanal is treated with excess ethanol and acid?


Draw structures of the following derivative.

The ethylene ketal of hexan-3-one


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one 


Draw the structure of the given derivative.

The ethylene ketal of hexan-3-one


Give an example of the reaction in the following case.

Oxime


Give an example of the reaction in the following case.

Imine


Which of the following will not be formed when calcium formate is distilled with calcium acetate?


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