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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Alkenes and carbonyl compounds , both contain a π bond but alkenes show electrophilic addition reactions whereas carbonyl compounds show nucleophilic addition reactions. Explain. - Chemistry

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प्रश्न

Alkenes   and carbonyl compounds , both contain a π bond but alkenes show electrophilic addition reactions whereas carbonyl compounds show nucleophilic addition reactions. Explain.

टीपा लिहा
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उत्तर

Carbonyl group is polar in nature. Due to larger electronegativity of oxygen as compared to carbon, carbon acquires partial positive charge while O acquires partial negative charge.

Because of slight positive charge on C atom, it is attacked by nucleophiles and, therefore, undergoes nucleophilic addition reaction.

Ethylenic double bond is a non-polar bond and is a source of electrons. Therefore, it is attacked by electrophiles and undergoes electrophilic addition reactions.

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पाठ 12: Aldehydes, Ketones and Carboxylic Acids - Multiple Choice Questions (Type - I) [पृष्ठ १७३]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 12 Aldehydes, Ketones and Carboxylic Acids
Multiple Choice Questions (Type - I) | Q 31 | पृष्ठ १७३

संबंधित प्रश्‍न

Write balanced chemical equations for action of ammonia on - formaldehyde


Arrange the following in the increasing order of their reactivity towards nucleophilic addition reaction:

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Predict the product of the following reaction:


What is meant by the following term? Give an example of the reaction in the following case.

Ketal


What is meant by the following term? Give an example of the reaction in the following case.

Imine


Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.

Excess ethanol and acid


Arrange the following compounds in increasing order of their property as indicated:

Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards HCN)


How will you bring about the following conversion in not more than two steps?

Bromobenzene to 1-Phenylethanol


What is the action of the following reagents on ethanoic acid?

1) `LiAlH_4"/"H_3O^+`

2) `PCl_3 , "heat"`

3) `P_2O_5, "heat"`


How will you convert sodium acetate to methane?


Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):

(i)  

(ii)  

(iii)  

(iv) 


Which one of the following gives only one monochloro derivative?


A Idol condensation will not be observed in


Which among the following is most reactive to give nucleophilic addition?


Arrange the following in the increasing order of their property indicated:

Ethanal, Propanone, Propanal, Butanone (reactivity towards nucleophilic addition)


The following questions are case-based questions. Read the passage carefully and answer the questions that follow:

The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols.

Answer the following:

(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)

(b) Why carboxylic acid is a stronger acid than phenol? (1)

(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)

CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\],  \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]

(ii) Write a chemical test to distinguish between propanal and propanone. (1)

OR

(c) Write the main product in the following: (2)

(i)
(ii)

The product of the following reaction is

\[\begin{array}{cc}
\ce{O}\phantom{.........}\\
||\phantom{.........}\\
\ce{C2H5 - C - CH3 ->[H2/Ni][\Delta] \phantom{..}?}\end{array}\]


Draw the structure of the following derivative.

Acetaldehydedimethylacetal


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one 


The major product of the following reaction is:


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