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प्रश्न
Alkenes 
and carbonyl compounds 
, both contain a π bond but alkenes show electrophilic addition reactions whereas carbonyl compounds show nucleophilic addition reactions. Explain.
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उत्तर
Carbonyl group is polar in nature. Due to larger electronegativity of oxygen as compared to carbon, carbon acquires partial positive charge while O acquires partial negative charge.
Because of slight positive charge on C atom, it is attacked by nucleophiles and, therefore, undergoes nucleophilic addition reaction.
Ethylenic double bond is a non-polar bond and is a source of electrons. Therefore, it is attacked by electrophiles and undergoes electrophilic addition reactions.
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संबंधित प्रश्न
Write balanced chemical equations for action of ammonia on - formaldehyde
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C6H5COCH3, CH3-CHO, CH3COCH3
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The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
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Draw the structure of the following derivative.
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Draw structure of the following derivative.
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Draw structures of the given derivatives.
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Draw structure of the following derivative.
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