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प्रश्न
Predict the product of the following reaction:
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उत्तर
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संबंधित प्रश्न
Draw the structure of the semicarbazone of ethanal.
What is meant by the following term? Give an example of the reaction in the following case.
Cyanohydrin
What is meant by the following term? Give an example of the reaction in the following case.
Hemiacetal
What is meant by the following term? Give an example of the reaction in the following case.
Schiff’s base
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
PhMgBr and then H3O+
Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards HCN)
How will you bring about the following conversion in not more than two steps?
Bromobenzene to 1-Phenylethanol
Give plausible explanation for the following:
There are two −NH2 groups in semicarbazide. However, only one is involved in the formation of semicarbazones.
Write balanced chemical equations for action of ammonia on - acetone
What is the action of the following reagents on ethanoic acid?
1) `LiAlH_4"/"H_3O^+`
2) `PCl_3 , "heat"`
3) `P_2O_5, "heat"`
Benzaldehyde can be obtained from benzal chloride. Write reactions for obtaining benzalchloride and then benzaldehyde from it.
Paraldehyde is formed as a result of polymerisation:-
Write the name of product formed, when acetone is treated with 2, 4-dinitrophenyl hydrazine.
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Write the structure of the product formed when acetone reacts with 2, 4 DNP reagent.
Draw structure of the following derivative.
The ethylene ketal of hexane-3-one
Draw structure of the following derivative:
Acetaldehydedimethylacetal
The major product of the following reaction is:
