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प्रश्न
Acetone, Acetaldehyde, Benzaldehyde, Acetophenone – reactivity towards addition of HCN.
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उत्तर
Acetone, acetaldehyde, benzaldehyde, acetophenone - Reactivity with HCN
\[\begin{array}{c}\ce{CH3-C-CH3}\\\ce{||}\\\ce{O}\end{array}
\begin{array}{c}\ce{CH3-CHO}\\\ce{||}\\\ce{O}\end{array}\ce{C6H5CHO}\begin{array}{c}\ce{CH3-C-C6H5}\\\ce{||}\\\ce{O}\end{array}\]
Nucelophile addition by HCN is strongest for aldehyde than ketones. Also, acetophenone is more sterically hindered than acetone, hence comparatively less nucleophilic similarly C6 H5CHO i -s less reactive towards nucleophilic addition than CH3CHO.
\[\begin{array}{c}\ce{CH3-C-C6H5}\\\ce{||}\\\ce{O}\end{array}
\begin{array}{c}\ce{< CH3-C -CH3}\\\ce{||}\\\ce{O}\end{array}\ce{<C6H5CHO < CH3CHO}\]
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संबंधित प्रश्न
Arrange the following compound in increasing order of its reactivity in nucleophilic addition reactions.
Ethanal, Propanal, Propanone, Butanone.
Hint: Consider steric effect and electronic effect.
Predict the product of the following reaction:
What is meant by the following term? Give an example of the reaction in the following case.
Acetal
What is the action of the following reagents on ethanoic acid?
1) `LiAlH_4"/"H_3O^+`
2) `PCl_3 , "heat"`
3) `P_2O_5, "heat"`
Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):
(i) 
(ii) 
(iii) 
(iv) 
Carboxylic acids contain carbonyl group but do not show the nucleophilic addition reaction like aldehydes or ketones. Why?
Reaction of aqueous sodium hydroxide on chlorobenzene gives which of the following products?
In the following reaction
\[\ce{Carbonyl compound + MeOH <=>[HCl] acetal}\]
Rate of the reaction is the highest for ______.
The product of following reaction is
\[\ce{CH3 - CH = CH - CH2 - CHO ->[i) LiAlH4][ii) H3O+]}\] ______?
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
