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प्रश्न
How will you bring about the following conversion in not more than two steps?
Bromobenzene to 1-Phenylethanol
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उत्तर
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संबंधित प्रश्न
What is meant by the following term? Give an example of the reaction in the following case.
Acetal
What is meant by the following term? Give an example of the reaction in the following case.
2, 4-DNP-derivative
What is meant by the following term? Give an example of the reaction in the following case.
Schiff’s base
Complete the synthesis by giving missing starting material, reagent or product.
\[\ce{C6H5CHO ->[H2NCONHNH2]}\]
Write the main product formed when propanal reacts with the following reagents:
H2N- NH2 followed by heating with KOH in ethylene glycol.
Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):
(i) 
(ii) 
(iii) 
(iv) 
Alkenes 
and carbonyl compounds 
, both contain a π bond but alkenes show electrophilic addition reactions whereas carbonyl compounds show nucleophilic addition reactions. Explain.
Which one of the following gives only one monochloro derivative?
Arrange the following in the increasing order of their property indicated:
Ethanal, Propanone, Propanal, Butanone (reactivity towards nucleophilic addition)
What happens when ethanal is treated with excess ethanol and acid?
The product of following reaction is
\[\ce{CH3 - CH = CH - CH2 - CHO ->[i) LiAlH4][ii) H3O+]}\] ______?
Which of the following is most reactive in nucleophilic addition reactions?
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Aldehydes and ketones react with hydroxylamine to form ______.
Write the structure of the product formed when acetone reacts with 2, 4 DNP reagent.
Draw structures of the following derivatives.
Acetaldehydedimethylacetal
Draw structure of the following derivative:
Acetaldehydedimethylacetal
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Give an example of the reaction in the following case.
Imine
