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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

How will you bring about the following conversion in not more than two steps? Benzaldehyde to 3-Phenylpropan-1-ol

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प्रश्न

How will you bring about the following conversion in not more than two steps?

Benzaldehyde to 3-Phenylpropan-1-ol

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पाठ 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ २५६]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.15 (vii) | पृष्ठ २५६

संबंधित प्रश्‍न

Write the products formed when CH3CHO reacts with the following reagents: CH3CHO in the presence of dilute NaOH


What is meant by the following term? Give an example of the reaction in the following case.

Aldol


Which of the following compounds would undergo aldol condensation, which the Cannizzaro reaction and which neither? Write the structures of the expected products of aldol condensation and Cannizzaro reaction.

  1. Methanal
  2. 2-Methylpentanal
  3. Benzaldehyde
  4. Benzophenone
  5. Cyclohexanone
  6. 1-Phenylpropanone
  7. Phenylacetaldehyde
  8. Butan-1-ol
  9. 2, 2-Dimethylbutanal

Describe the following:

Cross aldol condensation


 Why is alpha (α) hydrogen of carbonyl compounds acidic in nature?


Write a chemical equation for the following reaction: 
Propanone is treated with dilute Ba( OH)2.


Cannizaro’s reaction is not given by ______.


Which of the following compounds do not undergo aldol condensation?

(i) \[\ce{CH3 - CHO}\]

(ii)  

(iii)  \[\begin{array}{cc}
\phantom{}\ce{O}\\
\phantom{}||\\
\ce{CH3 - C - CH3}
\end{array}\]

(iv) \[\begin{array}{cc}
\phantom{}\ce{CH3}\\
|\phantom{...}\\
\ce{CH3 - C - CHO}\phantom{..}\\
|\phantom{...}\\
\phantom{}\ce{CH3}\\
\end{array}\]


Which of the following conversions can be carried out by Clemmensen Reduction?

(i) Benzaldehyde into benzyl alcohol

(ii) Cyclohexanone into cyclohexane

(iii) Benzoyl chloride into benzaldehyde

(iv) Benzophenone into diphenyl methane


When liquid ‘A’ is treated with a freshly prepared ammoniacal silver nitrate solution, it gives bright silver mirror. The liquid forms a white crystalline solid on treatment with sodium hydrogensulphite. Liquid ‘B’ also forms a white crystalline solid with sodium hydrogensulphite but it does not give test with ammoniacal silver nitrate. Which of the two liquids is aldehyde? Write the chemical equations of these reactions also.


Identify A and B from the following reaction:

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\phantom{}\ce{2CH3 - C = O ->[Ba(OH)2] A ->[Δ] B + H2O}
\end{array}\]


\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]

The product in the above reaction is:


Explain the aldol condensation of ethanal.


Which of the following does not give aldol condensation reaction?


Identify A and B:


Write a note on the aldol condensation reaction of acetaldehyde.


What is aldol condensation? Explain it with suitable examples.


Which one of the following undergoes reaction with 50% sodiumhydroxide solution to give the corresponding alcohol and acid:


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