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Karnataka Board PUCPUC Science 2nd PUC Class 12

How will you bring about the following conversion in not more than two steps? Benzaldehyde to 3-Phenylpropan-1-ol

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Question

How will you bring about the following conversion in not more than two steps?

Benzaldehyde to 3-Phenylpropan-1-ol

Chemical Equations/Structures
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Solution 1

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Solution 2

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Chapter 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [Page 256]

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NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.15 (vii) | Page 256

RELATED QUESTIONS

Which of the following compounds would undergo aldol condensation, which the Cannizzaro reaction and which neither? Write the structures of the expected products of aldol condensation and Cannizzaro reaction.

  1. Methanal
  2. 2-Methylpentanal
  3. Benzaldehyde
  4. Benzophenone
  5. Cyclohexanone
  6. 1-Phenylpropanone
  7. Phenylacetaldehyde
  8. Butan-1-ol
  9. 2, 2-Dimethylbutanal

How will you convert ethanal into the following compound?

But-2-enal


Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.


How will you bring about the following conversion in not more than two steps?

Ethanol to 3-Hydroxybutanal


Describe the following:

Cross aldol condensation


 Why is alpha (α) hydrogen of carbonyl compounds acidic in nature?


Write chemical equations of the following reaction : 

Propanone is treated with dilute Ba (OH)2-.


Write a chemical equation for the following reaction: 
Propanone is treated with dilute Ba( OH)2.


Which product is formed when the compound  is treated with concentrated aqueous \[\ce{KOH}\] solution?


Which of the following compounds do not undergo aldol condensation?

(i) \[\ce{CH3 - CHO}\]

(ii)  

(iii)  \[\begin{array}{cc}
\phantom{}\ce{O}\\
\phantom{}||\\
\ce{CH3 - C - CH3}
\end{array}\]

(iv) \[\begin{array}{cc}
\phantom{}\ce{CH3}\\
|\phantom{...}\\
\ce{CH3 - C - CHO}\phantom{..}\\
|\phantom{...}\\
\phantom{}\ce{CH3}\\
\end{array}\]


Why are carboxylic acids more acidic than alcohols or phenols although all of them have hydrogen atom attached to a oxygen atom \[\ce{(-O-H)}\]?


Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction.

Reason: Aromatic aldehydes are almost as reactive as formaldehyde.


Give reasons to support the answer:

Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.


Identify A and B from the following reaction:

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\phantom{}\ce{2CH3 - C = O ->[Ba(OH)2] A ->[Δ] B + H2O}
\end{array}\]


Explain the aldol condensation of ethanal.


Which of the following compounds will undergo self-condensation in the presence of dilute NaOH solution?


Write a note on the aldol condensation reaction of acetaldehyde.


Which one of the following undergoes reaction with 50% sodiumhydroxide solution to give the corresponding alcohol and acid:


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