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Karnataka Board PUCPUC Science 2nd PUC Class 12

How will you bring about the following conversion in not more than two steps? Benzaldehyde to 3-Phenylpropan-1-ol

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Question

How will you bring about the following conversion in not more than two steps?

Benzaldehyde to 3-Phenylpropan-1-ol

Chemical Equations/Structures
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Solution 1

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Solution 2

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Chapter 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [Page 256]

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NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.15 (vii) | Page 256

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How will you convert ethanal into the following compound?

But-2-enal


Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.


Complete the synthesis by giving missing starting material, reagent or product.

\[\begin{array}{cc}
\ce{C6H5CHO}\phantom{............}\\
\phantom{........}\ce{+\phantom{......}\ce{->[dil.NaOH][\Delta]}}\phantom{...}\\
\ce{CH3CH2CHO}\phantom{............}
\end{array}\]


Cannizaro’s reaction is not given by ______.


Which product is formed when the compound  is treated with concentrated aqueous \[\ce{KOH}\] solution?


Compounds A and C in the following reaction are:

\[\ce{CH3CHO ->[(i) CH3MgBr][(ii) H2O] (A) ->[H2SO4, Δ] (B) ->[Hydroboration oxidation] (C)}\]


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(i) \[\ce{CH3 - CHO}\]

(ii)  

(iii)  \[\begin{array}{cc}
\phantom{}\ce{O}\\
\phantom{}||\\
\ce{CH3 - C - CH3}
\end{array}\]

(iv) \[\begin{array}{cc}
\phantom{}\ce{CH3}\\
|\phantom{...}\\
\ce{CH3 - C - CHO}\phantom{..}\\
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\end{array}\]


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What product will be formed on reaction of propanal with 2-methylpropanal in the presence of \[\ce{NaOH}\]? What products will be formed? Write the name of the reaction also.


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Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.


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The major product of the following reaction is:


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When acetaldehyde is treated with dilute NaOH, the following reaction is observed.

\[\begin{array}{cc}
\ce{2CH3 - CHO ->[dil.NaOH] CH3 - CH - CH2 - CHO}\\
\phantom{...............}|\\
\phantom{.................}\ce{OH}
\end{array}\]

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Write a note on the aldol condensation reaction of acetaldehyde.


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