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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

How will you bring about the following conversion in not more than two steps? Benzaldehyde to 3-Phenylpropan-1-ol

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प्रश्न

How will you bring about the following conversion in not more than two steps?

Benzaldehyde to 3-Phenylpropan-1-ol

रासायनिक समीकरण/संरचनाएँ
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अध्याय 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ २५६]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.15 (vii) | पृष्ठ २५६

संबंधित प्रश्न

Write the products formed when CH3CHO reacts with the following reagents: CH3CHO in the presence of dilute NaOH


What is meant by the following term? Give an example of the reaction in the following case.

Aldol


Which of the following compounds would undergo aldol condensation, which the Cannizzaro reaction and which neither? Write the structures of the expected products of aldol condensation and Cannizzaro reaction.

  1. Methanal
  2. 2-Methylpentanal
  3. Benzaldehyde
  4. Benzophenone
  5. Cyclohexanone
  6. 1-Phenylpropanone
  7. Phenylacetaldehyde
  8. Butan-1-ol
  9. 2, 2-Dimethylbutanal

Complete the synthesis by giving missing starting material, reagent or product.

\[\begin{array}{cc}
\ce{C6H5CHO}\phantom{............}\\
\phantom{........}\ce{+\phantom{......}\ce{->[dil.NaOH][\Delta]}}\phantom{...}\\
\ce{CH3CH2CHO}\phantom{............}
\end{array}\]


Write chemical equations of the following reaction : 

Propanone is treated with dilute Ba (OH)2-.


Write chemical equations of the following reaction :
Benzoyl chloride is hydrogenated in the presence of `"Pd"/(BaSO_4)`


Write a chemical equation for the following reaction: 
Propanone is treated with dilute Ba( OH)2.


What is substituted imine called?


Cannizaro’s reaction is not given by ______.


Compounds A and C in the following reaction are:

\[\ce{CH3CHO ->[(i) CH3MgBr][(ii) H2O] (A) ->[H2SO4, Δ] (B) ->[Hydroboration oxidation] (C)}\]


What product will be formed on reaction of propanal with 2-methylpropanal in the presence of \[\ce{NaOH}\]? What products will be formed? Write the name of the reaction also.


Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction.

Reason: Aromatic aldehydes are almost as reactive as formaldehyde.


Give reasons to support the answer:

Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.


Identify A and B from the following reaction:

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\phantom{}\ce{2CH3 - C = O ->[Ba(OH)2] A ->[Δ] B + H2O}
\end{array}\]


Convert the following:

Acetaldehyde to But-2-enal


When acetaldehyde is treated with dilute NaOH, the following reaction is observed.

\[\begin{array}{cc}
\ce{2CH3 - CHO ->[dil.NaOH] CH3 - CH - CH2 - CHO}\\
\phantom{...............}|\\
\phantom{.................}\ce{OH}
\end{array}\]

  1. What are the functional groups in the product?
  2. Can another product be formed during the same reaction? (Deduce the answer by doing atomic audit of reactant and product).
  3. Is this an addition reaction or condensation reaction?

Write a note on the aldol condensation reaction of acetaldehyde.


What is aldol condensation? Explain it with suitable examples.


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