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प्रश्न
Identify A and B from the following reaction:
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\phantom{}\ce{2CH3 - C = O ->[Ba(OH)2] A ->[Δ] B + H2O}
\end{array}\]
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उत्तर
\[\begin{array}{cc}
\phantom{..........}\ce{CH3}\phantom{..................}\ce{CH3}\phantom{.......}\ce{CH3}\phantom{....................}\ce{CH3}\phantom{......}\ce{CH3}\phantom{...........}\\
\phantom{..................}|\phantom{.....................}|\phantom{...........}|\phantom{.......................}|\phantom{..........}|\phantom{.....................}\\
\phantom{}\ce{2CH3 - C = O ->[Ba(OH)2] CH3 - C - CH2 - C = O ->[Δ/-H2O]\ce{CH3 - C = CH - C = O + H2O}}\\
\phantom{.............................}|\phantom{.................................}\ce{\underset{(B)}{4-Methypent-3-en-2-one}}\phantom{}\\
\ce{\underset{\underset{(A)}{4-Hydroxy-4-methyl pentan-2-one}}{OH}}\phantom{........................}
\end{array}\]
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संबंधित प्रश्न
What is meant by the following term? Give an example of the reaction in the following case.
Aldol
Which of the following compounds would undergo aldol condensation, which the Cannizzaro reaction and which neither? Write the structures of the expected products of aldol condensation and Cannizzaro reaction.
- Methanal
- 2-Methylpentanal
- Benzaldehyde
- Benzophenone
- Cyclohexanone
- 1-Phenylpropanone
- Phenylacetaldehyde
- Butan-1-ol
- 2, 2-Dimethylbutanal
How will you convert ethanal into the following compound?
Butane-1, 3-diol
How will you convert ethanal into the following compound?
But-2-enal
Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.
Give reasons Acetylation of aniline reduces its activation effect.
Why is alpha (α) hydrogen of carbonyl compounds acidic in nature?
Write chemical equations of the following reaction :
Benzoyl chloride is hydrogenated in the presence of `"Pd"/(BaSO_4)`
Write a chemical equation for the following reaction:
Propanone is treated with dilute Ba( OH)2.
What is substituted imine called?
Explain aldol condensation reaction in detail.
Cannizaro’s reaction is not given by ______.
Which product is formed when the compound 
is treated with concentrated aqueous \[\ce{KOH}\] solution?
Compounds A and C in the following reaction are:
\[\ce{CH3CHO ->[(i) CH3MgBr][(ii) H2O] (A) ->[H2SO4, Δ] (B) ->[Hydroboration oxidation] (C)}\]
Which of the following conversions can be carried out by Clemmensen Reduction?
(i) Benzaldehyde into benzyl alcohol
(ii) Cyclohexanone into cyclohexane
(iii) Benzoyl chloride into benzaldehyde
(iv) Benzophenone into diphenyl methane
Why is there a large difference in the boiling points of butanal and butan-1-ol?
What product will be formed on reaction of propanal with 2-methylpropanal in the presence of \[\ce{NaOH}\]? What products will be formed? Write the name of the reaction also.
Give reasons to support the answer:
Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.
Cross aldol condensation occurs between
Convert the following:
Acetaldehyde to But-2-enal
Predict the reagent for carrying out the following transformations:
Ethanal to 3-hydroxy butanal
\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]
The product in the above reaction is:
The major product of the following reaction is:
Explain the aldol condensation of ethanal.
Which of the following does not give aldol condensation reaction?
When acetaldehyde is treated with dilute NaOH, the following reaction is observed.
\[\begin{array}{cc}
\ce{2CH3 - CHO ->[dil.NaOH] CH3 - CH - CH2 - CHO}\\
\phantom{...............}|\\
\phantom{.................}\ce{OH}
\end{array}\]
- What are the functional groups in the product?
- Can another product be formed during the same reaction? (Deduce the answer by doing atomic audit of reactant and product).
- Is this an addition reaction or condensation reaction?
Write a note on the aldol condensation reaction of acetaldehyde.
