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प्रश्न
How will you convert ethanal into the following compound?
Butane-1, 3-diol
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उत्तर
\[\ce{\underset{Ethanal}{2CH3CHO}->[Dil.NaOH][Aldol condensation]\underset{3-Hydroxybutanal}{\overset{4}{C}H3\overset{3}{C}HOH - \overset{2}{C}H2 - \overset{1}{C}HO}->[NaBH4][(Reduction)]\underset{Butane-1, 3-diol}{\overset{4}{C}H3 - \overset{3}{C}HOH - \overset{2}{C}H2 - \overset{1}{C}H2OH}}\]
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संबंधित प्रश्न
Write the products formed when CH3CHO reacts with the following reagents: CH3CHO in the presence of dilute NaOH
What is meant by the following term? Give an example of the reaction in the following case.
Aldol
How will you convert ethanal into the following compound?
But-2-enal
Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.
How will you bring about the following conversion in not more than two steps?
Ethanol to 3-Hydroxybutanal
How will you bring about the following conversion in not more than two steps?
Benzaldehyde to 3-Phenylpropan-1-ol
Complete the synthesis by giving missing starting material, reagent or product.
\[\begin{array}{cc}
\ce{C6H5CHO}\phantom{............}\\
\phantom{........}\ce{+\phantom{......}\ce{->[dil.NaOH][\Delta]}}\phantom{...}\\
\ce{CH3CH2CHO}\phantom{............}
\end{array}\]
Write chemical equations of the following reaction :
Propanone is treated with dilute Ba (OH)2-.
What is substituted imine called?
Explain aldol condensation reaction in detail.
Why is there a large difference in the boiling points of butanal and butan-1-ol?
Compound ‘A’ was prepared by oxidation of compound ‘B’ with alkaline \[\ce{KMnO4}\]. Compound ‘A’ on reduction with lithium aluminium hydride gets converted back to compound ‘B’. When compound ‘A’ is heated with compound B in the presence of \[\ce{H2SO4}\] it produces fruity smell of compound C to which family the compounds ‘A’, ‘B’ and ‘C’ belong to?
Give reasons to support the answer:
Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.
\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]
The product in the above reaction is:
The major product of the following reaction is:
Identify A and B:
When acetaldehyde is treated with dilute NaOH, the following reaction is observed.
\[\begin{array}{cc}
\ce{2CH3 - CHO ->[dil.NaOH] CH3 - CH - CH2 - CHO}\\
\phantom{...............}|\\
\phantom{.................}\ce{OH}
\end{array}\]
- What are the functional groups in the product?
- Can another product be formed during the same reaction? (Deduce the answer by doing atomic audit of reactant and product).
- Is this an addition reaction or condensation reaction?
