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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Which product is formed when the compound is treated with concentrated aqueous KOH solution?

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प्रश्न

Which product is formed when the compound  is treated with concentrated aqueous \[\ce{KOH}\] solution?

विकल्प

MCQ
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उत्तर

Explanation:

Benzaldehyde is having no a hydrogen. So, on reaction with aqueous KOH solution, it undergoes Cannizzaro’s reaction. One molecule of aldehyde is reduced and other is

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अध्याय 12: Aldehydes, Ketones and Carboxylic Acids - Multiple Choice Questions (Type - I) [पृष्ठ १६९]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 12 Aldehydes, Ketones and Carboxylic Acids
Multiple Choice Questions (Type - I) | Q 7 | पृष्ठ १६९

संबंधित प्रश्न

Write the products formed when CH3CHO reacts with the following reagents: CH3CHO in the presence of dilute NaOH


What is meant by the following term? Give an example of the reaction in the following case.

Aldol


How will you convert ethanal into the following compound?

Butane-1, 3-diol


How will you convert ethanal into the following compound?

But-2-enal


Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.


How will you bring about the following conversion in not more than two steps?

Ethanol to 3-Hydroxybutanal


Complete the synthesis by giving missing starting material, reagent or product.

\[\begin{array}{cc}
\ce{C6H5CHO}\phantom{............}\\
\phantom{........}\ce{+\phantom{......}\ce{->[dil.NaOH][\Delta]}}\phantom{...}\\
\ce{CH3CH2CHO}\phantom{............}
\end{array}\]


Give reasons  Acetylation of aniline reduces its activation effect.


Write chemical equations of the following reaction :
Benzoyl chloride is hydrogenated in the presence of `"Pd"/(BaSO_4)`


Compound ‘A’ was prepared by oxidation of compound ‘B’ with alkaline \[\ce{KMnO4}\]. Compound ‘A’ on reduction with lithium aluminium hydride gets converted back to compound ‘B’. When compound ‘A’ is heated with compound B in the presence of \[\ce{H2SO4}\] it produces fruity smell of compound C to which family the compounds ‘A’, ‘B’ and ‘C’ belong to?


Assertion: The α-hydrogen atom in carbonyl compounds is less acidic.

Reason: The anion formed after the loss of α-hydrogen atom is resonance stabilised.


Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction.

Reason: Aromatic aldehydes are almost as reactive as formaldehyde.


Which of the following gives aldol con~ensation reaction?


Convert the following:

Acetaldehyde to But-2-enal


Predict the reagent for carrying out the following transformations:

Ethanal to 3-hydroxy butanal


Which of the following compounds will undergo self-condensation in the presence of dilute NaOH solution?


When acetaldehyde is treated with dilute NaOH, the following reaction is observed.

\[\begin{array}{cc}
\ce{2CH3 - CHO ->[dil.NaOH] CH3 - CH - CH2 - CHO}\\
\phantom{...............}|\\
\phantom{.................}\ce{OH}
\end{array}\]

  1. What are the functional groups in the product?
  2. Can another product be formed during the same reaction? (Deduce the answer by doing atomic audit of reactant and product).
  3. Is this an addition reaction or condensation reaction?

What is aldol condensation? Explain it with suitable examples.


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