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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Which product is formed when the compound is treated with concentrated aqueous KOH solution? - Chemistry

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प्रश्न

Which product is formed when the compound  is treated with concentrated aqueous \[\ce{KOH}\] solution?

पर्याय

MCQ
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उत्तर

Explanation:

Benzaldehyde is having no a hydrogen. So, on reaction with aqueous KOH solution, it undergoes Cannizzaro’s reaction. One molecule of aldehyde is reduced and other is

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पाठ 12: Aldehydes, Ketones and Carboxylic Acids - Multiple Choice Questions (Type - I) [पृष्ठ १६९]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 12 Aldehydes, Ketones and Carboxylic Acids
Multiple Choice Questions (Type - I) | Q 7 | पृष्ठ १६९

संबंधित प्रश्‍न

Write the products formed when CH3CHO reacts with the following reagents: CH3CHO in the presence of dilute NaOH


Which of the following compounds would undergo aldol condensation, which the Cannizzaro reaction and which neither? Write the structures of the expected products of aldol condensation and Cannizzaro reaction.

  1. Methanal
  2. 2-Methylpentanal
  3. Benzaldehyde
  4. Benzophenone
  5. Cyclohexanone
  6. 1-Phenylpropanone
  7. Phenylacetaldehyde
  8. Butan-1-ol
  9. 2, 2-Dimethylbutanal

How will you bring about the following conversion in not more than two steps?

Benzaldehyde to 3-Phenylpropan-1-ol


Describe the following:

Cross aldol condensation


Complete the synthesis by giving missing starting material, reagent or product.

\[\begin{array}{cc}
\ce{C6H5CHO}\phantom{............}\\
\phantom{........}\ce{+\phantom{......}\ce{->[dil.NaOH][\Delta]}}\phantom{...}\\
\ce{CH3CH2CHO}\phantom{............}
\end{array}\]


 Why is alpha (α) hydrogen of carbonyl compounds acidic in nature?


Write chemical equations of the following reaction : 

Propanone is treated with dilute Ba (OH)2-.


Cannizaro’s reaction is not given by ______.


Compounds A and C in the following reaction are:

\[\ce{CH3CHO ->[(i) CH3MgBr][(ii) H2O] (A) ->[H2SO4, Δ] (B) ->[Hydroboration oxidation] (C)}\]


Why is there a large difference in the boiling points of butanal and butan-1-ol?


Compound ‘A’ was prepared by oxidation of compound ‘B’ with alkaline \[\ce{KMnO4}\]. Compound ‘A’ on reduction with lithium aluminium hydride gets converted back to compound ‘B’. When compound ‘A’ is heated with compound B in the presence of \[\ce{H2SO4}\] it produces fruity smell of compound C to which family the compounds ‘A’, ‘B’ and ‘C’ belong to?


Why are carboxylic acids more acidic than alcohols or phenols although all of them have hydrogen atom attached to a oxygen atom \[\ce{(-O-H)}\]?


Convert the following:

Acetaldehyde to But-2-enal


Predict the reagent for carrying out the following transformations:

Ethanal to 3-hydroxy butanal


\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]

The product in the above reaction is:


Which of the following does not give aldol condensation reaction?


Which of the following compounds will undergo self-condensation in the presence of dilute NaOH solution?


When acetaldehyde is treated with dilute NaOH, the following reaction is observed.

\[\begin{array}{cc}
\ce{2CH3 - CHO ->[dil.NaOH] CH3 - CH - CH2 - CHO}\\
\phantom{...............}|\\
\phantom{.................}\ce{OH}
\end{array}\]

  1. What are the functional groups in the product?
  2. Can another product be formed during the same reaction? (Deduce the answer by doing atomic audit of reactant and product).
  3. Is this an addition reaction or condensation reaction?

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