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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Which product is formed when the compound is treated with concentrated aqueous KOH solution?

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प्रश्न

Which product is formed when the compound  is treated with concentrated aqueous \[\ce{KOH}\] solution?

पर्याय

MCQ
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उत्तर

Explanation:

Benzaldehyde is having no a hydrogen. So, on reaction with aqueous KOH solution, it undergoes Cannizzaro’s reaction. One molecule of aldehyde is reduced and other is

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पाठ 12: Aldehydes, Ketones and Carboxylic Acids - Multiple Choice Questions (Type - I) [पृष्ठ १६९]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 12 Aldehydes, Ketones and Carboxylic Acids
Multiple Choice Questions (Type - I) | Q 7 | पृष्ठ १६९

संबंधित प्रश्‍न

What is meant by the following term? Give an example of the reaction in the following case.

Aldol


Which of the following compounds would undergo aldol condensation, which the Cannizzaro reaction and which neither? Write the structures of the expected products of aldol condensation and Cannizzaro reaction.

  1. Methanal
  2. 2-Methylpentanal
  3. Benzaldehyde
  4. Benzophenone
  5. Cyclohexanone
  6. 1-Phenylpropanone
  7. Phenylacetaldehyde
  8. Butan-1-ol
  9. 2, 2-Dimethylbutanal

Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.


How will you bring about the following conversion in not more than two steps?

Ethanol to 3-Hydroxybutanal


Describe the following:

Cross aldol condensation


Give reasons  Acetylation of aniline reduces its activation effect.


What is substituted imine called?


Cannizaro’s reaction is not given by ______.


Why is there a large difference in the boiling points of butanal and butan-1-ol?


What product will be formed on reaction of propanal with 2-methylpropanal in the presence of \[\ce{NaOH}\]? What products will be formed? Write the name of the reaction also.


Identify A and B from the following reaction:

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\phantom{}\ce{2CH3 - C = O ->[Ba(OH)2] A ->[Δ] B + H2O}
\end{array}\]


Predict the reagent for carrying out the following transformations:

Ethanal to 3-hydroxy butanal


\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]

The product in the above reaction is:


The major product of the following reaction is:


Why is the α-hydrogens of aldehydes and ketones are acidic in nature?


When acetaldehyde is treated with dilute NaOH, the following reaction is observed.

\[\begin{array}{cc}
\ce{2CH3 - CHO ->[dil.NaOH] CH3 - CH - CH2 - CHO}\\
\phantom{...............}|\\
\phantom{.................}\ce{OH}
\end{array}\]

  1. What are the functional groups in the product?
  2. Can another product be formed during the same reaction? (Deduce the answer by doing atomic audit of reactant and product).
  3. Is this an addition reaction or condensation reaction?

Write a note on the aldol condensation reaction of acetaldehyde.


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