मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction. Reason: Aromatic aldehydes are almost as reactive as formaldehyde.

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प्रश्न

Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction.

Reason: Aromatic aldehydes are almost as reactive as formaldehyde.

पर्याय

  • Assertion and reason both are correct and reason is correct explanation of assertion.

  • Assertion and reason both are wrong statements.

  • Assertion is correct statement but reason is wrong statement.

  • Assertion is wrong statement but reason is correct statement.

  • Assertion and reason both are correct statements but reasson is not correct explanation of assertion.

MCQ
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उत्तर

Assertion is correct statement but reason is wrong statement.

Explanation:

There is no alpha hydrogen atom in the Cannizaro process. Formaldehyde and aromatic aldehydes do not contain alpha hydrogen. It proceeds through the Cannizaro reaction. Formaldehyde is the most reactive of all aldehydes.

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पाठ 12: Aldehydes, Ketones and Carboxylic Acids - Multiple Choice Questions (Type - I) [पृष्ठ १७६]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 12 Aldehydes, Ketones and Carboxylic Acids
Multiple Choice Questions (Type - I) | Q 45 | पृष्ठ १७६

संबंधित प्रश्‍न

Which of the following compounds would undergo aldol condensation, which the Cannizzaro reaction and which neither? Write the structures of the expected products of aldol condensation and Cannizzaro reaction.

  1. Methanal
  2. 2-Methylpentanal
  3. Benzaldehyde
  4. Benzophenone
  5. Cyclohexanone
  6. 1-Phenylpropanone
  7. Phenylacetaldehyde
  8. Butan-1-ol
  9. 2, 2-Dimethylbutanal

How will you convert ethanal into the following compound?

Butane-1, 3-diol


How will you bring about the following conversion in not more than two steps?

Benzaldehyde to 3-Phenylpropan-1-ol


Write chemical equations of the following reaction : 

Propanone is treated with dilute Ba (OH)2-.


What is substituted imine called?


Cannizaro’s reaction is not given by ______.


Which of the following compounds do not undergo aldol condensation?

(i) \[\ce{CH3 - CHO}\]

(ii)  

(iii)  \[\begin{array}{cc}
\phantom{}\ce{O}\\
\phantom{}||\\
\ce{CH3 - C - CH3}
\end{array}\]

(iv) \[\begin{array}{cc}
\phantom{}\ce{CH3}\\
|\phantom{...}\\
\ce{CH3 - C - CHO}\phantom{..}\\
|\phantom{...}\\
\phantom{}\ce{CH3}\\
\end{array}\]


Which of the following conversions can be carried out by Clemmensen Reduction?

(i) Benzaldehyde into benzyl alcohol

(ii) Cyclohexanone into cyclohexane

(iii) Benzoyl chloride into benzaldehyde

(iv) Benzophenone into diphenyl methane


Why is there a large difference in the boiling points of butanal and butan-1-ol?


What product will be formed on reaction of propanal with 2-methylpropanal in the presence of \[\ce{NaOH}\]? What products will be formed? Write the name of the reaction also.


Why are carboxylic acids more acidic than alcohols or phenols although all of them have hydrogen atom attached to a oxygen atom \[\ce{(-O-H)}\]?


Cross aldol condensation occurs between


Convert the following:

Acetaldehyde to But-2-enal


\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]

The product in the above reaction is:


Which of the following does not give aldol condensation reaction?


Which of the following compounds will undergo self-condensation in the presence of dilute NaOH solution?


Why is the α-hydrogens of aldehydes and ketones are acidic in nature?


Which one of the following undergoes reaction with 50% sodiumhydroxide solution to give the corresponding alcohol and acid:


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