मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction. Reason: Aromatic aldehydes are almost as reactive as formaldehyde.

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प्रश्न

Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction.

Reason: Aromatic aldehydes are almost as reactive as formaldehyde.

पर्याय

  • Assertion and reason both are correct and reason is correct explanation of assertion.

  • Assertion and reason both are wrong statements.

  • Assertion is correct statement but reason is wrong statement.

  • Assertion is wrong statement but reason is correct statement.

  • Assertion and reason both are correct statements but reasson is not correct explanation of assertion.

MCQ
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उत्तर

Assertion is correct statement but reason is wrong statement.

Explanation:

There is no alpha hydrogen atom in the Cannizaro process. Formaldehyde and aromatic aldehydes do not contain alpha hydrogen. It proceeds through the Cannizaro reaction. Formaldehyde is the most reactive of all aldehydes.

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पाठ 12: Aldehydes, Ketones and Carboxylic Acids - Multiple Choice Questions (Type - I) [पृष्ठ १७६]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 12 Aldehydes, Ketones and Carboxylic Acids
Multiple Choice Questions (Type - I) | Q 45 | पृष्ठ १७६

संबंधित प्रश्‍न

Write the products formed when CH3CHO reacts with the following reagents: CH3CHO in the presence of dilute NaOH


How will you bring about the following conversion in not more than two steps?

Benzaldehyde to 3-Phenylpropan-1-ol


Give reasons  Acetylation of aniline reduces its activation effect.


Compounds A and C in the following reaction are:

\[\ce{CH3CHO ->[(i) CH3MgBr][(ii) H2O] (A) ->[H2SO4, Δ] (B) ->[Hydroboration oxidation] (C)}\]


Which of the following compounds do not undergo aldol condensation?

(i) \[\ce{CH3 - CHO}\]

(ii)  

(iii)  \[\begin{array}{cc}
\phantom{}\ce{O}\\
\phantom{}||\\
\ce{CH3 - C - CH3}
\end{array}\]

(iv) \[\begin{array}{cc}
\phantom{}\ce{CH3}\\
|\phantom{...}\\
\ce{CH3 - C - CHO}\phantom{..}\\
|\phantom{...}\\
\phantom{}\ce{CH3}\\
\end{array}\]


Compound ‘A’ was prepared by oxidation of compound ‘B’ with alkaline \[\ce{KMnO4}\]. Compound ‘A’ on reduction with lithium aluminium hydride gets converted back to compound ‘B’. When compound ‘A’ is heated with compound B in the presence of \[\ce{H2SO4}\] it produces fruity smell of compound C to which family the compounds ‘A’, ‘B’ and ‘C’ belong to?


Give reasons to support the answer:

Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.


Cross aldol condensation occurs between


Which of the following gives aldol con~ensation reaction?


Identify A and B from the following reaction:

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\phantom{}\ce{2CH3 - C = O ->[Ba(OH)2] A ->[Δ] B + H2O}
\end{array}\]


Predict the reagent for carrying out the following transformations:

Ethanal to 3-hydroxy butanal


\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]

The product in the above reaction is:


Explain Aldol condensation of ethanal.


Which of the following does not give aldol condensation reaction?


Assertion (A): The final product in Aldol condensation is always α, β-unsaturated carbonyl compound.

Reason (R): α, β-unsaturated carbonyl compounds are stabilised due to conjugation.


What is aldol condensation? Explain it with suitable examples.


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