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प्रश्न
Identify A and B from the following reaction:
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\phantom{}\ce{2CH3 - C = O ->[Ba(OH)2] A ->[Δ] B + H2O}
\end{array}\]
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उत्तर
\[\begin{array}{cc}
\phantom{..........}\ce{CH3}\phantom{..................}\ce{CH3}\phantom{.......}\ce{CH3}\phantom{....................}\ce{CH3}\phantom{......}\ce{CH3}\phantom{...........}\\
\phantom{..................}|\phantom{.....................}|\phantom{...........}|\phantom{.......................}|\phantom{..........}|\phantom{.....................}\\
\phantom{}\ce{2CH3 - C = O ->[Ba(OH)2] CH3 - C - CH2 - C = O ->[Δ/-H2O]\ce{CH3 - C = CH - C = O + H2O}}\\
\phantom{.............................}|\phantom{.................................}\ce{\underset{(B)}{4-Methypent-3-en-2-one}}\phantom{}\\
\ce{\underset{\underset{(A)}{4-Hydroxy-4-methyl pentan-2-one}}{OH}}\phantom{........................}
\end{array}\]
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संबंधित प्रश्न
Write the products formed when CH3CHO reacts with the following reagents: CH3CHO in the presence of dilute NaOH
How will you convert ethanal into the following compound?
But-2-enal
Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.
How will you bring about the following conversion in not more than two steps?
Ethanol to 3-Hydroxybutanal
Complete the synthesis by giving missing starting material, reagent or product.
\[\begin{array}{cc}
\ce{C6H5CHO}\phantom{............}\\
\phantom{........}\ce{+\phantom{......}\ce{->[dil.NaOH][\Delta]}}\phantom{...}\\
\ce{CH3CH2CHO}\phantom{............}
\end{array}\]
Give reasons Acetylation of aniline reduces its activation effect.
Write chemical equations of the following reaction :
Propanone is treated with dilute Ba (OH)2-.
Write a chemical equation for the following reaction:
Propanone is treated with dilute Ba( OH)2.
Explain aldol condensation reaction in detail.
Compounds A and C in the following reaction are:
\[\ce{CH3CHO ->[(i) CH3MgBr][(ii) H2O] (A) ->[H2SO4, Δ] (B) ->[Hydroboration oxidation] (C)}\]
Which of the following conversions can be carried out by Clemmensen Reduction?
(i) Benzaldehyde into benzyl alcohol
(ii) Cyclohexanone into cyclohexane
(iii) Benzoyl chloride into benzaldehyde
(iv) Benzophenone into diphenyl methane
Why is there a large difference in the boiling points of butanal and butan-1-ol?
Compound ‘A’ was prepared by oxidation of compound ‘B’ with alkaline \[\ce{KMnO4}\]. Compound ‘A’ on reduction with lithium aluminium hydride gets converted back to compound ‘B’. When compound ‘A’ is heated with compound B in the presence of \[\ce{H2SO4}\] it produces fruity smell of compound C to which family the compounds ‘A’, ‘B’ and ‘C’ belong to?
Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction.
Reason: Aromatic aldehydes are almost as reactive as formaldehyde.
When liquid ‘A’ is treated with a freshly prepared ammoniacal silver nitrate solution, it gives bright silver mirror. The liquid forms a white crystalline solid on treatment with sodium hydrogensulphite. Liquid ‘B’ also forms a white crystalline solid with sodium hydrogensulphite but it does not give test with ammoniacal silver nitrate. Which of the two liquids is aldehyde? Write the chemical equations of these reactions also.
Predict the reagent for carrying out the following transformations:
Ethanal to 3-hydroxy butanal
\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]
The product in the above reaction is:
The major product of the following reaction is:
Explain Aldol condensation of ethanal.
Assertion (A): The final product in Aldol condensation is always α, β-unsaturated carbonyl compound.
Reason (R): α, β-unsaturated carbonyl compounds are stabilised due to conjugation.
Identify A and B:
Write a note on the aldol condensation reaction of acetaldehyde.
