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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

How will you convert ethanal into the following compound? Butane-1, 3-diol

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प्रश्न

How will you convert ethanal into the following compound?

Butane-1, 3-diol

रासायनिक समीकरणे/रचना
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उत्तर

\[\ce{\underset{Ethanal}{2CH3CHO}->[Dil.NaOH][Aldol condensation]\underset{3-Hydroxybutanal}{\overset{4}{C}H3\overset{3}{C}HOH - \overset{2}{C}H2 - \overset{1}{C}HO}->[NaBH4][(Reduction)]\underset{Butane-1, 3-diol}{\overset{4}{C}H3 - \overset{3}{C}HOH - \overset{2}{C}H2 - \overset{1}{C}H2OH}}\]

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पाठ 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ २५६]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.8 (i) | पृष्ठ २५६

संबंधित प्रश्‍न

Write the products formed when CH3CHO reacts with the following reagents: CH3CHO in the presence of dilute NaOH


How will you convert ethanal into the following compound?

But-2-enal


Describe the following:

Cross aldol condensation


 Why is alpha (α) hydrogen of carbonyl compounds acidic in nature?


Explain aldol condensation reaction in detail.


Which product is formed when the compound  is treated with concentrated aqueous \[\ce{KOH}\] solution?


Compounds A and C in the following reaction are:

\[\ce{CH3CHO ->[(i) CH3MgBr][(ii) H2O] (A) ->[H2SO4, Δ] (B) ->[Hydroboration oxidation] (C)}\]


Which of the following compounds do not undergo aldol condensation?

(i) \[\ce{CH3 - CHO}\]

(ii)  

(iii)  \[\begin{array}{cc}
\phantom{}\ce{O}\\
\phantom{}||\\
\ce{CH3 - C - CH3}
\end{array}\]

(iv) \[\begin{array}{cc}
\phantom{}\ce{CH3}\\
|\phantom{...}\\
\ce{CH3 - C - CHO}\phantom{..}\\
|\phantom{...}\\
\phantom{}\ce{CH3}\\
\end{array}\]


Which of the following conversions can be carried out by Clemmensen Reduction?

(i) Benzaldehyde into benzyl alcohol

(ii) Cyclohexanone into cyclohexane

(iii) Benzoyl chloride into benzaldehyde

(iv) Benzophenone into diphenyl methane


Why is there a large difference in the boiling points of butanal and butan-1-ol?


Assertion: The α-hydrogen atom in carbonyl compounds is less acidic.

Reason: The anion formed after the loss of α-hydrogen atom is resonance stabilised.


Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction.

Reason: Aromatic aldehydes are almost as reactive as formaldehyde.


Give reasons to support the answer:

Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.


Cross aldol condensation occurs between


Predict the reagent for carrying out the following transformations:

Ethanal to 3-hydroxy butanal


Which of the following does not give aldol condensation reaction?


Which of the following compounds will undergo self-condensation in the presence of dilute NaOH solution?


Why is the α-hydrogens of aldehydes and ketones are acidic in nature?


Assertion (A): The final product in Aldol condensation is always α, β-unsaturated carbonyl compound.

Reason (R): α, β-unsaturated carbonyl compounds are stabilised due to conjugation.


Write a note on the aldol condensation reaction of acetaldehyde.


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