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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

How will you convert ethanal into the following compound? But-2-enal

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प्रश्न

How will you convert ethanal into the following compound?

But-2-enal

Carry out the following conversion: 

Ethanal to But-2-enal.

How will you bring about the following conversion?

Ethanal to but-2-enal.

रासायनिक समीकरणे/रचना
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उत्तर १

\[\ce{\underset{Ethanal}{2CH3CHO}->[(i) dil.NaOH][(ii) H+, \Delta]\underset{But-2-enal}{CH3CH = CHCHO}}\]

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उत्तर २

\[\ce{\underset{Ethanal}{2CH3CHO}->[dil.NaOH][Aldol condensation]\underset{Hydroxybutanal}{\overset{4}{C}H3 - \overset{3}{C}HOH - \overset{2}{C}H2 - \overset{1}{C}HO}->[H3O+/\Delta][-H2O]\underset{But-2-enal}{CH3 - CH = CH - CHO}}\]

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  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ २५६]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.8 (ii) | पृष्ठ २५६

संबंधित प्रश्‍न

A compound 'A' of molecular formula C2H3OCl undergoes a series of reactions as shown below. Write the structures of A, B, C and D in the following reactions :


Write the products formed when CH3CHO reacts with the following reagents: CH3CHO in the presence of dilute NaOH


Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.


 Why is alpha (α) hydrogen of carbonyl compounds acidic in nature?


Write chemical equations of the following reaction : 

Propanone is treated with dilute Ba (OH)2-.


Write a chemical equation for the following reaction: 
Propanone is treated with dilute Ba( OH)2.


What is substituted imine called?


Cannizaro’s reaction is not given by ______.


Which product is formed when the compound  is treated with concentrated aqueous \[\ce{KOH}\] solution?


Which of the following conversions can be carried out by Clemmensen Reduction?

(i) Benzaldehyde into benzyl alcohol

(ii) Cyclohexanone into cyclohexane

(iii) Benzoyl chloride into benzaldehyde

(iv) Benzophenone into diphenyl methane


Why are carboxylic acids more acidic than alcohols or phenols although all of them have hydrogen atom attached to a oxygen atom \[\ce{(-O-H)}\]?


Convert the following:

Acetaldehyde to But-2-enal


Predict the reagent for carrying out the following transformations:

Ethanal to 3-hydroxy butanal


Assertion (A): The final product in Aldol condensation is always α, β-unsaturated carbonyl compound.

Reason (R): α, β-unsaturated carbonyl compounds are stabilised due to conjugation.


When acetaldehyde is treated with dilute NaOH, the following reaction is observed.

\[\begin{array}{cc}
\ce{2CH3 - CHO ->[dil.NaOH] CH3 - CH - CH2 - CHO}\\
\phantom{...............}|\\
\phantom{.................}\ce{OH}
\end{array}\]

  1. What are the functional groups in the product?
  2. Can another product be formed during the same reaction? (Deduce the answer by doing atomic audit of reactant and product).
  3. Is this an addition reaction or condensation reaction?

Write a note on the aldol condensation reaction of acetaldehyde.


Which one of the following undergoes reaction with 50% sodiumhydroxide solution to give the corresponding alcohol and acid:


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