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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

How will you convert ethanal into the following compound? But-2-enoic acid

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प्रश्न

How will you convert ethanal into the following compound?

But-2-enoic acid

रासायनिक समीकरणे/रचना
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उत्तर

\[\ce{\underset{Ethanal}{2CH3CHO}->[dil.NaOH][Aldol condensation ]\underset{but-2-enal}{CH3CH = CHCHO}->[Ag(NH3)^+2OH-][Tollens' reagent]\underset{But-2-enoic acid}{CH3CH = CHCO2H}}\]

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पाठ 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ २५६]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.8 (iii) | पृष्ठ २५६

संबंधित प्रश्‍न

Distinguish between:

C6H5-COCH3 and C6H5-CHO


Predict the products of the following reactions :


Give a simple chemical test to distinguish between the following pair of compounds:

Propanal and Propanone


Out of CH3CH2 – CO – CH2 – CH3 and CH3CH2 – CH2 – CO – CH3, which gives iodoform test?


Give a simple chemical test to distinguish between the following pair of compounds:

Benzoic acid and Ethyl benzoate


An organic compound contains 69.77% carbon, 11.63% hydrogen and rest oxygen. The molecular mass of the compound is 86. It does not reduce Tollens’ reagent but forms an addition compound with sodium hydrogensulphite and give positive iodoform test. On vigorous oxidation it gives ethanoic and propanoic acid. Write the possible structure of the compound.


Complete the synthesis by giving missing starting material, reagent or product.


Alkenes decolourise bromine water in presence of CCl4 due to formation of ______.


Which of the following compounds will give butanone on oxidation with alkaline \[\ce{KMnO4}\] solution?


Which of the following compounds gives a positive Tollen's test but negative Fehling's test?


Acetone and acetaldehyde are differentiated by


Fehilng's test is positive for


A hydrocarbon (A) with molecular formula C5H10 on ozonolysis gives two products (B) and (C). Both (B) and (C) give a yellow precipitate when heated with iodine in presence of NaOH while only (B) give a silver mirror on reaction with Tollen’s reagent.

  1. Identify (A), (B) and (C).
  2. Write the reaction of B with Tollen’s reagent.
  3. Write the equation for iodoform test for C.
  4. Write down the equation for aldol condensation reaction of B and C.

What is the composition of Fehling's reagent?


Which among the above compound/s does/do not form Silver mirror when treated with Tollen's reagent?


The reagent that can be used to distinguish acetophenone and benzophenone is ______.


An organic compound 'A' with the molecular formula C4H8O2 undergoes acid hydrolysis to form two compounds 'B' and 'C'. Oxidation of 'C' with acidified potassium permanganate also produces 'B'. Sodium salt of 'B' on heating with soda lime gives methane.

  1. Identify 'A', 'B' and 'C'.
  2. Out of 'B' and 'C', which will have higher boiling point? Give reason.

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