मराठी

Convert the following: Acetaldehyde to But-2-enal

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प्रश्न

Convert the following:

Acetaldehyde to But-2-enal

लघु उत्तर
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उत्तर

Aldol condensation (in presence of dil. \[\ce{NaOH}\]) followed by dehydration.

\[\begin{array}{cc}
\phantom{}\ce{\underset{Acetaldehyde}{CH3CHO} ->[dil. NaOH] CH3 - CH - CH2 - CHO ->[Δ][-H2O] \underset{\underset{(Adol condensation product)}{But-2-enal}}{CH3 - CH} = CH - CHO}\\
|\phantom{.........................}\\
\ce{\underset{\underset{(Adol)}{3-Hydroxybutanal}}{OH}}\phantom{.......................}\\
\end{array}\]

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2021-2022 (March) Term 2 - Delhi Set 2

व्हिडिओ ट्यूटोरियलVIEW ALL [1]

संबंधित प्रश्‍न

A compound 'A' of molecular formula C2H3OCl undergoes a series of reactions as shown below. Write the structures of A, B, C and D in the following reactions :


Write the products formed when CH3CHO reacts with the following reagents: CH3CHO in the presence of dilute NaOH


Explain aldol condensation reaction in detail.


Cannizaro’s reaction is not given by ______.


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When liquid ‘A’ is treated with a freshly prepared ammoniacal silver nitrate solution, it gives bright silver mirror. The liquid forms a white crystalline solid on treatment with sodium hydrogensulphite. Liquid ‘B’ also forms a white crystalline solid with sodium hydrogensulphite but it does not give test with ammoniacal silver nitrate. Which of the two liquids is aldehyde? Write the chemical equations of these reactions also.


\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]

The product in the above reaction is:


Explain the aldol condensation of ethanal.


When acetaldehyde is treated with dilute NaOH, the following reaction is observed.

\[\begin{array}{cc}
\ce{2CH3 - CHO ->[dil.NaOH] CH3 - CH - CH2 - CHO}\\
\phantom{...............}|\\
\phantom{.................}\ce{OH}
\end{array}\]

  1. What are the functional groups in the product?
  2. Can another product be formed during the same reaction? (Deduce the answer by doing atomic audit of reactant and product).
  3. Is this an addition reaction or condensation reaction?

Which one of the following undergoes reaction with 50% sodiumhydroxide solution to give the corresponding alcohol and acid:


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