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प्रश्न
Convert the following:
Acetaldehyde to But-2-enal
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उत्तर
Aldol condensation (in presence of dil. \[\ce{NaOH}\]) followed by dehydration.
\[\begin{array}{cc}
\phantom{}\ce{\underset{Acetaldehyde}{CH3CHO} ->[dil. NaOH] CH3 - CH - CH2 - CHO ->[Δ][-H2O] \underset{\underset{(Adol condensation product)}{But-2-enal}}{CH3 - CH} = CH - CHO}\\
|\phantom{.........................}\\
\ce{\underset{\underset{(Adol)}{3-Hydroxybutanal}}{OH}}\phantom{.......................}\\
\end{array}\]
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संबंधित प्रश्न
How will you convert ethanal into the following compound?
But-2-enal
Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.
Complete the synthesis by giving missing starting material, reagent or product.
\[\begin{array}{cc}
\ce{C6H5CHO}\phantom{............}\\
\phantom{........}\ce{+\phantom{......}\ce{->[dil.NaOH][\Delta]}}\phantom{...}\\
\ce{CH3CH2CHO}\phantom{............}
\end{array}\]
Write chemical equations of the following reaction :
Benzoyl chloride is hydrogenated in the presence of `"Pd"/(BaSO_4)`
Which product is formed when the compound 
is treated with concentrated aqueous \[\ce{KOH}\] solution?
Assertion: The α-hydrogen atom in carbonyl compounds is less acidic.
Reason: The anion formed after the loss of α-hydrogen atom is resonance stabilised.
Which of the following gives aldol con~ensation reaction?
The major product of the following reaction is:
Assertion (A): The final product in Aldol condensation is always α, β-unsaturated carbonyl compound.
Reason (R): α, β-unsaturated carbonyl compounds are stabilised due to conjugation.
Identify A and B:
