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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Complete the synthesis by giving missing starting material, reagent or product. CA6HA5CHO....................+......→Δdil⋅NaOH...CHA3CHA2CHO............ - Chemistry

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प्रश्न

Complete the synthesis by giving missing starting material, reagent or product.

\[\begin{array}{cc}
\ce{C6H5CHO}\phantom{............}\\
\phantom{........}\ce{+\phantom{......}\ce{->[dil.NaOH][\Delta]}}\phantom{...}\\
\ce{CH3CH2CHO}\phantom{............}
\end{array}\]

रासायनिक समीकरण/संरचनाएँ
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उत्तर

\[\begin{array}{cc}
\phantom{......................................................}\ce{CH3}\\
\phantom{...................................................}|\\
\ce{\underset{Benzaldehyde}{C6H5CHO} + \underset{Propanal}{CH3CH2CHO} ->[dil.NaOH][Claisen-Schimdt reaction]\underset{2-Methyl-3-phenyl-prop-2-enal}{C6H5\overset{3}{C}H = \overset{2}{C} - \overset{1}{C}HO}}
\end{array}\]

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अध्याय 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ २५७]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.17 (vii) | पृष्ठ २५७

संबंधित प्रश्न

Write the products formed when CH3CHO reacts with the following reagents: CH3CHO in the presence of dilute NaOH


How will you convert ethanal into the following compound?

But-2-enal


Write chemical equations of the following reaction : 

Propanone is treated with dilute Ba (OH)2-.


Write chemical equations of the following reaction :
Benzoyl chloride is hydrogenated in the presence of `"Pd"/(BaSO_4)`


Write a chemical equation for the following reaction: 
Propanone is treated with dilute Ba( OH)2.


What is substituted imine called?


Cannizaro’s reaction is not given by ______.


Which product is formed when the compound  is treated with concentrated aqueous \[\ce{KOH}\] solution?


Which of the following compounds do not undergo aldol condensation?

(i) \[\ce{CH3 - CHO}\]

(ii)  

(iii)  \[\begin{array}{cc}
\phantom{}\ce{O}\\
\phantom{}||\\
\ce{CH3 - C - CH3}
\end{array}\]

(iv) \[\begin{array}{cc}
\phantom{}\ce{CH3}\\
|\phantom{...}\\
\ce{CH3 - C - CHO}\phantom{..}\\
|\phantom{...}\\
\phantom{}\ce{CH3}\\
\end{array}\]


Why is there a large difference in the boiling points of butanal and butan-1-ol?


What product will be formed on reaction of propanal with 2-methylpropanal in the presence of \[\ce{NaOH}\]? What products will be formed? Write the name of the reaction also.


Why are carboxylic acids more acidic than alcohols or phenols although all of them have hydrogen atom attached to a oxygen atom \[\ce{(-O-H)}\]?


Which of the following gives aldol con~ensation reaction?


The major product of the following reaction is:


Explain Aldol condensation of ethanal.


Which of the following compounds will undergo self-condensation in the presence of dilute NaOH solution?


Assertion (A): The final product in Aldol condensation is always α, β-unsaturated carbonyl compound.

Reason (R): α, β-unsaturated carbonyl compounds are stabilised due to conjugation.


When acetaldehyde is treated with dilute NaOH, the following reaction is observed.

\[\begin{array}{cc}
\ce{2CH3 - CHO ->[dil.NaOH] CH3 - CH - CH2 - CHO}\\
\phantom{...............}|\\
\phantom{.................}\ce{OH}
\end{array}\]

  1. What are the functional groups in the product?
  2. Can another product be formed during the same reaction? (Deduce the answer by doing atomic audit of reactant and product).
  3. Is this an addition reaction or condensation reaction?

What is aldol condensation? Explain it with suitable examples.


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