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प्रश्न
Write a chemical equation for the following reaction:
Propanone is treated with dilute Ba( OH)2.
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उत्तर
This is a self-aldol condensation reaction.
\[\begin{array}{cc}
\phantom{............}\ce{CH3} \phantom{........................}\ce{CH3}\phantom{}\\
\phantom{..........................}|\phantom{............................}|\phantom{.................}\\
\ce{\underset{\text{Acetone or propanone}}{2CH3COCH3}<-->[Dil. Ba(OH)2] CH3-C-CH2-CO-CH3->[ ][\Delta]CH3-\underset{\text{4-methyl pent-3-en-2-one}}{C=CH-CO-CH3 }+ H2O}\\
\phantom{..................................}|\phantom{........................} \text{(Aldol condensation product)}\phantom{..}\\
\ce{\underset{\text{4-Hydroxy-4-methyl pentan-2-one(ketol)}}{OH}}\phantom{...................}\\
\end{array}\]
संबंधित प्रश्न
Write the products formed when CH3CHO reacts with the following reagents: CH3CHO in the presence of dilute NaOH
Which of the following compounds would undergo aldol condensation, which the Cannizzaro reaction and which neither? Write the structures of the expected products of aldol condensation and Cannizzaro reaction.
- Methanal
- 2-Methylpentanal
- Benzaldehyde
- Benzophenone
- Cyclohexanone
- 1-Phenylpropanone
- Phenylacetaldehyde
- Butan-1-ol
- 2, 2-Dimethylbutanal
How will you convert ethanal into the following compound?
But-2-enal
How will you bring about the following conversion in not more than two steps?
Ethanol to 3-Hydroxybutanal
Give reasons Acetylation of aniline reduces its activation effect.
Compound ‘A’ was prepared by oxidation of compound ‘B’ with alkaline \[\ce{KMnO4}\]. Compound ‘A’ on reduction with lithium aluminium hydride gets converted back to compound ‘B’. When compound ‘A’ is heated with compound B in the presence of \[\ce{H2SO4}\] it produces fruity smell of compound C to which family the compounds ‘A’, ‘B’ and ‘C’ belong to?
Give reasons to support the answer:
Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.
Convert the following:
Acetaldehyde to But-2-enal
\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]
The product in the above reaction is:
Explain Aldol condensation of ethanal.
