Advertisements
Advertisements
प्रश्न
Write a chemical equation for the following reaction:
Propanone is treated with dilute Ba( OH)2.
Advertisements
उत्तर
This is a self-aldol condensation reaction.
\[\begin{array}{cc}
\phantom{............}\ce{CH3} \phantom{........................}\ce{CH3}\phantom{}\\
\phantom{..........................}|\phantom{............................}|\phantom{.................}\\
\ce{\underset{\text{Acetone or propanone}}{2CH3COCH3}<-->[Dil. Ba(OH)2] CH3-C-CH2-CO-CH3->[ ][\Delta]CH3-\underset{\text{4-methyl pent-3-en-2-one}}{C=CH-CO-CH3 }+ H2O}\\
\phantom{..................................}|\phantom{........................} \text{(Aldol condensation product)}\phantom{..}\\
\ce{\underset{\text{4-Hydroxy-4-methyl pentan-2-one(ketol)}}{OH}}\phantom{...................}\\
\end{array}\]
संबंधित प्रश्न
A compound 'A' of molecular formula C2H3OCl undergoes a series of reactions as shown below. Write the structures of A, B, C and D in the following reactions :
What is meant by the following term? Give an example of the reaction in the following case.
Aldol
Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.
What is substituted imine called?
Which of the following conversions can be carried out by Clemmensen Reduction?
(i) Benzaldehyde into benzyl alcohol
(ii) Cyclohexanone into cyclohexane
(iii) Benzoyl chloride into benzaldehyde
(iv) Benzophenone into diphenyl methane
Why is there a large difference in the boiling points of butanal and butan-1-ol?
Assertion: The α-hydrogen atom in carbonyl compounds is less acidic.
Reason: The anion formed after the loss of α-hydrogen atom is resonance stabilised.
Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction.
Reason: Aromatic aldehydes are almost as reactive as formaldehyde.
Identify A and B from the following reaction:
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\phantom{}\ce{2CH3 - C = O ->[Ba(OH)2] A ->[Δ] B + H2O}
\end{array}\]
Assertion (A): The final product in Aldol condensation is always α, β-unsaturated carbonyl compound.
Reason (R): α, β-unsaturated carbonyl compounds are stabilised due to conjugation.
