Advertisements
Advertisements
प्रश्न
What product will be formed on reaction of propanal with 2-methylpropanal in the presence of \[\ce{NaOH}\]? What products will be formed? Write the name of the reaction also.
Advertisements
उत्तर
It is cross Aldol condensation
\[\begin{array}{cc}
\phantom{}\ce{CH3}\phantom{.................}\ce{OH}\phantom{...............}\ce{CH3}\phantom{..........}\ce{CH3}\phantom{............}\ce{CH3}\phantom{.}\ce{OH}\phantom{...}\ce{CH3}\phantom{....}\ce{H3C}\phantom{...}\\
\phantom{}|\phantom{....................}|\phantom{..................}|\phantom{.............}|\phantom{................}|\phantom{....}|\phantom{......}|\phantom{...........}\backslash\phantom{.}\\
\phantom{}\ce{CH3CH2CHO + CH3CHCH3 -> CH3CH2CH - C - CHO + CH2 - CH = C - CHO + CH3C - CH - C - CHO + CH - CH = C - CHO}\phantom{}\\
\phantom{................................................................}|\phantom{..........................}|\phantom{...........}/\phantom{.............}|\phantom{}\\
\phantom{...................................................................}\ce{CH3}\phantom{.......................}\ce{CH3}\phantom{...}\ce{H3C}\phantom{...............}\ce{CH3}\phantom{}
\end{array}\]
APPEARS IN
संबंधित प्रश्न
A compound 'A' of molecular formula C2H3OCl undergoes a series of reactions as shown below. Write the structures of A, B, C and D in the following reactions :
How will you convert ethanal into the following compound?
But-2-enal
Describe the following:
Cross aldol condensation
Complete the synthesis by giving missing starting material, reagent or product.
\[\begin{array}{cc}
\ce{C6H5CHO}\phantom{............}\\
\phantom{........}\ce{+\phantom{......}\ce{->[dil.NaOH][\Delta]}}\phantom{...}\\
\ce{CH3CH2CHO}\phantom{............}
\end{array}\]
Why is alpha (α) hydrogen of carbonyl compounds acidic in nature?
Write chemical equations of the following reaction :
Propanone is treated with dilute Ba (OH)2-.
Write chemical equations of the following reaction :
Benzoyl chloride is hydrogenated in the presence of `"Pd"/(BaSO_4)`
Write a chemical equation for the following reaction:
Propanone is treated with dilute Ba( OH)2.
Cannizaro’s reaction is not given by ______.
Which of the following compounds do not undergo aldol condensation?
(i) \[\ce{CH3 - CHO}\]
(ii) 
(iii) \[\begin{array}{cc}
\phantom{}\ce{O}\\
\phantom{}||\\
\ce{CH3 - C - CH3}
\end{array}\]
(iv) \[\begin{array}{cc}
\phantom{}\ce{CH3}\\
|\phantom{...}\\
\ce{CH3 - C - CHO}\phantom{..}\\
|\phantom{...}\\
\phantom{}\ce{CH3}\\
\end{array}\]
Compound ‘A’ was prepared by oxidation of compound ‘B’ with alkaline \[\ce{KMnO4}\]. Compound ‘A’ on reduction with lithium aluminium hydride gets converted back to compound ‘B’. When compound ‘A’ is heated with compound B in the presence of \[\ce{H2SO4}\] it produces fruity smell of compound C to which family the compounds ‘A’, ‘B’ and ‘C’ belong to?
Why are carboxylic acids more acidic than alcohols or phenols although all of them have hydrogen atom attached to a oxygen atom \[\ce{(-O-H)}\]?
When liquid ‘A’ is treated with a freshly prepared ammoniacal silver nitrate solution, it gives bright silver mirror. The liquid forms a white crystalline solid on treatment with sodium hydrogensulphite. Liquid ‘B’ also forms a white crystalline solid with sodium hydrogensulphite but it does not give test with ammoniacal silver nitrate. Which of the two liquids is aldehyde? Write the chemical equations of these reactions also.
Give reasons to support the answer:
Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.
Cross aldol condensation occurs between
\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]
The product in the above reaction is:
The major product of the following reaction is:
Which of the following does not give aldol condensation reaction?
Which one of the following undergoes reaction with 50% sodiumhydroxide solution to give the corresponding alcohol and acid:
