मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Which of the following compounds do not undergo aldol condensation?

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प्रश्न

Which of the following compounds do not undergo aldol condensation?

(i) \[\ce{CH3 - CHO}\]

(ii)  

(iii)  \[\begin{array}{cc}
\phantom{}\ce{O}\\
\phantom{}||\\
\ce{CH3 - C - CH3}
\end{array}\]

(iv) \[\begin{array}{cc}
\phantom{}\ce{CH3}\\
|\phantom{...}\\
\ce{CH3 - C - CHO}\phantom{..}\\
|\phantom{...}\\
\phantom{}\ce{CH3}\\
\end{array}\]

टीपा लिहा
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उत्तर

(ii)

(iv) \[\begin{array}{cc}
\phantom{}\ce{CH3}\\
|\phantom{...}\\
\ce{CH3 - C - CHO}\phantom{..}\\
|\phantom{...}\\
\phantom{}\ce{CH3}\\
\end{array}\]

Explanation:

In these compounds, a-hydrogen is absent. So, aldol condensation does not take place in these compounds.

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पाठ 12: Aldehydes, Ketones and Carboxylic Acids - Multiple Choice Questions (Type - I) [पृष्ठ १७१]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 12 Aldehydes, Ketones and Carboxylic Acids
Multiple Choice Questions (Type - I) | Q 13 | पृष्ठ १७१

संबंधित प्रश्‍न

What is meant by the following term? Give an example of the reaction in the following case.

Aldol


Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.


How will you bring about the following conversion in not more than two steps?

Ethanol to 3-Hydroxybutanal


 Why is alpha (α) hydrogen of carbonyl compounds acidic in nature?


Write chemical equations of the following reaction :
Benzoyl chloride is hydrogenated in the presence of `"Pd"/(BaSO_4)`


What is substituted imine called?


Which of the following conversions can be carried out by Clemmensen Reduction?

(i) Benzaldehyde into benzyl alcohol

(ii) Cyclohexanone into cyclohexane

(iii) Benzoyl chloride into benzaldehyde

(iv) Benzophenone into diphenyl methane


Why is there a large difference in the boiling points of butanal and butan-1-ol?


Compound ‘A’ was prepared by oxidation of compound ‘B’ with alkaline \[\ce{KMnO4}\]. Compound ‘A’ on reduction with lithium aluminium hydride gets converted back to compound ‘B’. When compound ‘A’ is heated with compound B in the presence of \[\ce{H2SO4}\] it produces fruity smell of compound C to which family the compounds ‘A’, ‘B’ and ‘C’ belong to?


Why are carboxylic acids more acidic than alcohols or phenols although all of them have hydrogen atom attached to a oxygen atom \[\ce{(-O-H)}\]?


Convert the following:

Acetaldehyde to But-2-enal


Predict the reagent for carrying out the following transformations:

Ethanal to 3-hydroxy butanal


Explain the aldol condensation of ethanal.


Which of the following does not give aldol condensation reaction?


Assertion (A): The final product in Aldol condensation is always α, β-unsaturated carbonyl compound.

Reason (R): α, β-unsaturated carbonyl compounds are stabilised due to conjugation.


When acetaldehyde is treated with dilute NaOH, the following reaction is observed.

\[\begin{array}{cc}
\ce{2CH3 - CHO ->[dil.NaOH] CH3 - CH - CH2 - CHO}\\
\phantom{...............}|\\
\phantom{.................}\ce{OH}
\end{array}\]

  1. What are the functional groups in the product?
  2. Can another product be formed during the same reaction? (Deduce the answer by doing atomic audit of reactant and product).
  3. Is this an addition reaction or condensation reaction?

Write a note on the aldol condensation reaction of acetaldehyde.


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