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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

How will you bring about the following conversion in not more than two steps? Ethanol to 3-Hydroxybutanal

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प्रश्न

How will you bring about the following conversion in not more than two steps?

Ethanol to 3-Hydroxybutanal

How will you convert the following:

Ethanol to 3-Hydroxybutanal

रासायनिक समीकरणे/रचना
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उत्तर १

\[\begin{array}{cc}
\phantom{...............................................................}\ce{OH}\\
\phantom{.............................................................}|\\
\ce{\underset{Ethanal}{CH3 - CH2 - OH}->[Mild oxidation][KMnO4/dil.H2SO4]\underset{(Two molecules)}{\underset{Acetaldehyde}{CH3 - CHO}}->[dil.OH-][warm]\underset{3-Hydroxybutanal}{CHO - CH2 - CH - CH3}}\
\end{array}\]

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उत्तर २

\[\begin{array}{cc}
\phantom{....................................}\ce{OH}\\
\phantom{..................................}|\\
\ce{CH3CH2OH ->[PCC] CH3CHO ->[dil NaOH][Aldol condensation] \underset{3-Hydroxybutanal}{CH3 - CH - CH2 - CHO}}
\end{array}\]

PCC = Pyridinechlorochromate

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  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ २५६]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.15 (iii) | पृष्ठ २५६

संबंधित प्रश्‍न

What is meant by the following term? Give an example of the reaction in the following case.

Aldol


How will you convert ethanal into the following compound?

Butane-1, 3-diol


How will you bring about the following conversion in not more than two steps?

Benzaldehyde to 3-Phenylpropan-1-ol


Give reasons  Acetylation of aniline reduces its activation effect.


 Why is alpha (α) hydrogen of carbonyl compounds acidic in nature?


Write chemical equations of the following reaction :
Benzoyl chloride is hydrogenated in the presence of `"Pd"/(BaSO_4)`


Why is there a large difference in the boiling points of butanal and butan-1-ol?


Compound ‘A’ was prepared by oxidation of compound ‘B’ with alkaline \[\ce{KMnO4}\]. Compound ‘A’ on reduction with lithium aluminium hydride gets converted back to compound ‘B’. When compound ‘A’ is heated with compound B in the presence of \[\ce{H2SO4}\] it produces fruity smell of compound C to which family the compounds ‘A’, ‘B’ and ‘C’ belong to?


Why are carboxylic acids more acidic than alcohols or phenols although all of them have hydrogen atom attached to a oxygen atom \[\ce{(-O-H)}\]?


Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction.

Reason: Aromatic aldehydes are almost as reactive as formaldehyde.


When liquid ‘A’ is treated with a freshly prepared ammoniacal silver nitrate solution, it gives bright silver mirror. The liquid forms a white crystalline solid on treatment with sodium hydrogensulphite. Liquid ‘B’ also forms a white crystalline solid with sodium hydrogensulphite but it does not give test with ammoniacal silver nitrate. Which of the two liquids is aldehyde? Write the chemical equations of these reactions also.


Give reasons to support the answer:

Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.


Predict the reagent for carrying out the following transformations:

Ethanal to 3-hydroxy butanal


\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]

The product in the above reaction is:


Which of the following does not give aldol condensation reaction?


Which of the following compounds will undergo self-condensation in the presence of dilute NaOH solution?


Why is the α-hydrogens of aldehydes and ketones are acidic in nature?


What is aldol condensation? Explain it with suitable examples.


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