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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Compounds A and C in the following reaction are: CHX3CHO→(ii) HX2O(i) CHX3MgBr(A)→HX2SOX4,Δ(B)→Hydroboration oxidation(C)

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प्रश्न

Compounds A and C in the following reaction are:

\[\ce{CH3CHO ->[(i) CH3MgBr][(ii) H2O] (A) ->[H2SO4, Δ] (B) ->[Hydroboration oxidation] (C)}\]

पर्याय

  • identical

  • positional isomers

  • functional isomers

  • optical isomers

MCQ
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उत्तर

positional isomers

Explanation:

Thus, \[\begin{array}{cc}
\ce{CH3CH - OH}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\] and  \[\ce{CH3 - CH2 - CH2OH}\] are positional isomers.

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पाठ 12: Aldehydes, Ketones and Carboxylic Acids - Multiple Choice Questions (Type - I) [पृष्ठ १७०]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 12 Aldehydes, Ketones and Carboxylic Acids
Multiple Choice Questions (Type - I) | Q 9 | पृष्ठ १७०

संबंधित प्रश्‍न

Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.


How will you bring about the following conversion in not more than two steps?

Ethanol to 3-Hydroxybutanal


Write chemical equations of the following reaction : 

Propanone is treated with dilute Ba (OH)2-.


What is substituted imine called?


Explain aldol condensation reaction in detail.


Cannizaro’s reaction is not given by ______.


Which of the following conversions can be carried out by Clemmensen Reduction?

(i) Benzaldehyde into benzyl alcohol

(ii) Cyclohexanone into cyclohexane

(iii) Benzoyl chloride into benzaldehyde

(iv) Benzophenone into diphenyl methane


What product will be formed on reaction of propanal with 2-methylpropanal in the presence of \[\ce{NaOH}\]? What products will be formed? Write the name of the reaction also.


Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction.

Reason: Aromatic aldehydes are almost as reactive as formaldehyde.


Give reasons to support the answer:

Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.


Cross aldol condensation occurs between


Identify A and B from the following reaction:

\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\phantom{}\ce{2CH3 - C = O ->[Ba(OH)2] A ->[Δ] B + H2O}
\end{array}\]


Convert the following:

Acetaldehyde to But-2-enal


Which of the following does not give aldol condensation reaction?


Assertion (A): The final product in Aldol condensation is always α, β-unsaturated carbonyl compound.

Reason (R): α, β-unsaturated carbonyl compounds are stabilised due to conjugation.


Identify A and B:


When acetaldehyde is treated with dilute NaOH, the following reaction is observed.

\[\begin{array}{cc}
\ce{2CH3 - CHO ->[dil.NaOH] CH3 - CH - CH2 - CHO}\\
\phantom{...............}|\\
\phantom{.................}\ce{OH}
\end{array}\]

  1. What are the functional groups in the product?
  2. Can another product be formed during the same reaction? (Deduce the answer by doing atomic audit of reactant and product).
  3. Is this an addition reaction or condensation reaction?

Write a note on the aldol condensation reaction of acetaldehyde.


What is aldol condensation? Explain it with suitable examples.


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