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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Compounds A and C in the following reaction are: CHX3CHO→(ii) HX2O(i) CHX3MgBr(A)→HX2SOX4,Δ(B)→Hydroboration oxidation(C) - Chemistry

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प्रश्न

Compounds A and C in the following reaction are:

\[\ce{CH3CHO ->[(i) CH3MgBr][(ii) H2O] (A) ->[H2SO4, Δ] (B) ->[Hydroboration oxidation] (C)}\]

पर्याय

  • identical

  • positional isomers

  • functional isomers

  • optical isomers

MCQ
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उत्तर

positional isomers

Explanation:

Thus, \[\begin{array}{cc}
\ce{CH3CH - OH}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\] and  \[\ce{CH3 - CH2 - CH2OH}\] are positional isomers.

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पाठ 12: Aldehydes, Ketones and Carboxylic Acids - Multiple Choice Questions (Type - I) [पृष्ठ १७०]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 12 Aldehydes, Ketones and Carboxylic Acids
Multiple Choice Questions (Type - I) | Q 9 | पृष्ठ १७०

संबंधित प्रश्‍न

What is meant by the following term? Give an example of the reaction in the following case.

Aldol


How will you convert ethanal into the following compound?

Butane-1, 3-diol


How will you convert ethanal into the following compound?

But-2-enal


How will you bring about the following conversion in not more than two steps?

Benzaldehyde to 3-Phenylpropan-1-ol


Give reasons  Acetylation of aniline reduces its activation effect.


 Why is alpha (α) hydrogen of carbonyl compounds acidic in nature?


Which product is formed when the compound  is treated with concentrated aqueous \[\ce{KOH}\] solution?


Which of the following compounds do not undergo aldol condensation?

(i) \[\ce{CH3 - CHO}\]

(ii)  

(iii)  \[\begin{array}{cc}
\phantom{}\ce{O}\\
\phantom{}||\\
\ce{CH3 - C - CH3}
\end{array}\]

(iv) \[\begin{array}{cc}
\phantom{}\ce{CH3}\\
|\phantom{...}\\
\ce{CH3 - C - CHO}\phantom{..}\\
|\phantom{...}\\
\phantom{}\ce{CH3}\\
\end{array}\]


Which of the following conversions can be carried out by Clemmensen Reduction?

(i) Benzaldehyde into benzyl alcohol

(ii) Cyclohexanone into cyclohexane

(iii) Benzoyl chloride into benzaldehyde

(iv) Benzophenone into diphenyl methane


Compound ‘A’ was prepared by oxidation of compound ‘B’ with alkaline \[\ce{KMnO4}\]. Compound ‘A’ on reduction with lithium aluminium hydride gets converted back to compound ‘B’. When compound ‘A’ is heated with compound B in the presence of \[\ce{H2SO4}\] it produces fruity smell of compound C to which family the compounds ‘A’, ‘B’ and ‘C’ belong to?


Assertion: The α-hydrogen atom in carbonyl compounds is less acidic.

Reason: The anion formed after the loss of α-hydrogen atom is resonance stabilised.


Cross aldol condensation occurs between


Convert the following:

Acetaldehyde to But-2-enal


\[\ce{CH3-CH2-CHO ->[dil][alkali] Product}\]

The product in the above reaction is:


Explain Aldol condensation of ethanal.


Which of the following compounds will undergo self-condensation in the presence of dilute NaOH solution?


Why is the α-hydrogens of aldehydes and ketones are acidic in nature?


Identify A and B:


What is aldol condensation? Explain it with suitable examples.


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