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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Assertion: Aldehydes and ketones, both react with Tollen’s reagent to form silver mirror. Reason: Both, aldehydes and ketones contain a carbonyl group. - Chemistry

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प्रश्न

Assertion: Aldehydes and ketones, both react with Tollen’s reagent to form silver mirror.

Reason: Both, aldehydes and ketones contain a carbonyl group.

पर्याय

  • Assertion and reason both are correct and reason is correct explanation of assertion.

  • Assertion and reason both are wrong statements.

  • Assertion is correct statement but reason is wrong statement.

  • Assertion is wrong statement but reason is correct statement.

  • Assertion and reason both are correct statements but reasson is not correct explanation of assertion.

MCQ
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उत्तर

Assertion is wrong statement but reason is correct statement.

Explanation:

The silver mirror test can be used to determine Tollen's. \[\ce{[Ag(NH2)2]+ OH-}\]. Only aldehydes, not ketones, react with Tollen's reagent to create silver.

A silver mirror test is not given with this affirmative test.

The carbonyl group is present in both aldehyde and ketone.

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पाठ 12: Aldehydes, Ketones and Carboxylic Acids - Multiple Choice Questions (Type - I) [पृष्ठ १७६]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 12 Aldehydes, Ketones and Carboxylic Acids
Multiple Choice Questions (Type - I) | Q 46 | पृष्ठ १७६

संबंधित प्रश्‍न

On acid hydrolysis, propane nitrile gives.


Identify ‘A' and ‘B’ in the following reaction :

C6H5MgBr + C02 `(`> ‘A’   `(PCl_5)/()`> ‘B’

 


Write the structures of A and B in the following reactions


Name the reagents used in the following reactions:


Show how the following compound can be converted to benzoic acid.

Phenylethene (Styrene)


Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagent.

Tollens’ reagent


An organic compound (A) (molecular formula C8H16O2) was hydrolysed with dilute sulphuric acid to give a carboxylic acid (B) and an alcohol (C). Oxidation of (C) with chromic acid produced (B). (C) on dehydration gives but-1-ene. Write equations for the reactions involved.


How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.

m-Nitrobenzoic acid


How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.

p-Nitrobenzoic acid


How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.

Phenylacetic acid


How will you bring about the following conversion in not more than two steps?

Benazaldehyde to α-Hydroxyphenylacetic acid


Name the reagents used in the following reactions:


The functional group present in triacylglycerol is _______.


Match the reactions given in Column I with the suitable reagents given in Column II.

Column I
(Reactions)
Column II
(Reagents)
(i) Benzophenone Diphenylmethane (a) \[\ce{LiAlH4}\]
(ii) Benzaldehyde 1-Phenylethanol (b) \[\ce{DIBAL-H}\]
(iii) Cyclohexanone Cyclohexanol (c) \[\ce{Zn(Hg)/Conc. HCl}\]
(iv) Phenyl benzoate Benzaldehyde (d) \[\ce{CH3MgBr}\]

Substitution of one alkyl group by replacing hydrogen of primary amines


Which of the following substance produced acetaldehyde on dry distillation?


Match List - I with List - II.

List - I List - II
(a) \[\ce{->[CO,HCl][Anhyd. AlCl3/CuCl]}\] (i) Hell-Volhard-Zelinsky reaction
(b)
\[\begin{array}{cc}
\ce{O}\phantom{.................}\\
||\phantom{.................}\\
\ce{R - C - CH3 + NaOX ->}
\end{array}\]
(ii) Gattermann-Koch reaction
(c) \[\ce{R - CH2 - OH + R'COOH ->[Conc. H2SO4]}\] (iii) Haloform reaction
(d) \[\ce{R - CH2COOH ->[(i) X2/Red P][(ii) H2O]}\] (iv) Esterification

Choose the correct answer from the options given below.


Y is:


Hex-4-ene-2-ol on treatment with PCC gives 'A'. 'A' on reaction with sodium hypoiodite gives 'B', which on further heating with soda lime gives 'C. The compound 'C' is ______.


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