मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Assertion: Aldehydes and ketones, both react with Tollen’s reagent to form silver mirror. Reason: Both, aldehydes and ketones contain a carbonyl group.

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प्रश्न

Assertion: Aldehydes and ketones, both react with Tollen’s reagent to form silver mirror.

Reason: Both, aldehydes and ketones contain a carbonyl group.

पर्याय

  • Assertion and reason both are correct and reason is correct explanation of assertion.

  • Assertion and reason both are wrong statements.

  • Assertion is correct statement but reason is wrong statement.

  • Assertion is wrong statement but reason is correct statement.

  • Assertion and reason both are correct statements but reasson is not correct explanation of assertion.

MCQ
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उत्तर

Assertion is wrong statement but reason is correct statement.

Explanation:

The silver mirror test can be used to determine Tollen's. \[\ce{[Ag(NH2)2]+ OH-}\]. Only aldehydes, not ketones, react with Tollen's reagent to create silver.

A silver mirror test is not given with this affirmative test.

The carbonyl group is present in both aldehyde and ketone.

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पाठ 12: Aldehydes, Ketones and Carboxylic Acids - Multiple Choice Questions (Type - I) [पृष्ठ १७६]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 12 Aldehydes, Ketones and Carboxylic Acids
Multiple Choice Questions (Type - I) | Q 46 | पृष्ठ १७६

संबंधित प्रश्‍न

Identify ‘A' and ‘B’ in the following reaction :

C6H5MgBr + C02 `(`> ‘A’   `(PCl_5)/()`> ‘B’

 


Predict the products of the following reactions:


Name the reagents used in the following reactions:


Show how the following compound can be converted to benzoic acid.

Acetophenone


Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagent.

Tollens’ reagent


How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.

m-Nitrobenzoic acid


How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.

p-Nitrobenzoic acid


How will you bring about the following conversion in not more than two steps?

Benazaldehyde to α-Hydroxyphenylacetic acid


Complete the synthesis by giving missing starting material, reagent or product.


Name the reagents used in the following reactions:


What is the action of following reagents on glucose?
1. Bromine water
2. Hydroxylamine


The reagent which does not react with both, acetone and benzaldehyde.


Through which of the following reactions number of carbon atoms can be increased in the chain?

(i) Grignard reaction

(ii) Cannizaro’s reaction

(iii) Aldol condensation

(iv) HVZ reaction


Match the reactions given in Column I with the suitable reagents given in Column II.

Column I
(Reactions)
Column II
(Reagents)
(i) Benzophenone Diphenylmethane (a) \[\ce{LiAlH4}\]
(ii) Benzaldehyde 1-Phenylethanol (b) \[\ce{DIBAL-H}\]
(iii) Cyclohexanone Cyclohexanol (c) \[\ce{Zn(Hg)/Conc. HCl}\]
(iv) Phenyl benzoate Benzaldehyde (d) \[\ce{CH3MgBr}\]

Match List - I with List - II.

List - I List - II
(a) \[\ce{->[CO,HCl][Anhyd. AlCl3/CuCl]}\] (i) Hell-Volhard-Zelinsky reaction
(b)
\[\begin{array}{cc}
\ce{O}\phantom{.................}\\
||\phantom{.................}\\
\ce{R - C - CH3 + NaOX ->}
\end{array}\]
(ii) Gattermann-Koch reaction
(c) \[\ce{R - CH2 - OH + R'COOH ->[Conc. H2SO4]}\] (iii) Haloform reaction
(d) \[\ce{R - CH2COOH ->[(i) X2/Red P][(ii) H2O]}\] (iv) Esterification

Choose the correct answer from the options given below.


Alkaline hydrolysis of C4H8Cl2 gives a compound (A) which on heating with NaOH and I2 produces a yellow precipitate of CHI3. The compound (A) should be ______.


Hex-4-ene-2-ol on treatment with PCC gives 'A'. 'A' on reaction with sodium hypoiodite gives 'B', which on further heating with soda lime gives 'C. The compound 'C' is ______.


Fill in the blanks by choosing the appropriate words from those given in the brackets:

[stable, low, aldehyde, unstable, 6, 4, ethane, Clemmensen’s, 2, 3, carboxylic acid, high, propane, Rosenmund's]

The primary alcohols are easily oxidised first into ______ and then into ______.


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