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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

How Are the Following Compounds Prepared? benzaldehyde from benzene.

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प्रश्न

How are the following compounds prepared?

benzaldehyde from benzene

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उत्तर

(a) Benzaldehyde from benzene

Benzene
Gatterman Koch synthesis

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2012-2013 (March)

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संबंधित प्रश्‍न

Acetaldehyde, when treated with which among the following reagents does NOT undergo addition reaction?

(A) Ammonia

(B) Hydroxylamine

(C) Ammoniacal silver nitrate

(D) Semicarbazide


Arrange the following in the increasing order of their reactivity towards nucleophilic addition reaction:

C6H5COCH3, CH3-CHO, CH3COCH3


Arrange the following compound in increasing order of its reactivity in nucleophilic addition reactions.

Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.

Hint: Consider steric effect and electronic effect.


Predict the product of the following reaction:


What is meant by the following term? Give an example of the reaction in the following case.

Semicarbazone


What is meant by the following term? Give an example of the reaction in the following case.

Hemiacetal


Give plausible explanation for the following:

Cyclohexanone forms cyanohydrin in good yield but 2, 2, 6 trimethylcyclohexanone does not.


Complete the synthesis by giving missing starting material, reagent or product.

\[\ce{C6H5CHO ->[H2NCONHNH2]}\]


How are the following compounds prepared?

acetophenone from benzene


Write balanced chemical equations for action of ammonia on - acetone


What is the action of the following reagents on ethanoic acid?

1) `LiAlH_4"/"H_3O^+`

2) `PCl_3 , "heat"`

3) `P_2O_5, "heat"`


How will you convert sodium acetate to methane?


Give a simple chemical test to distinguish between 
 


Write a test to differentiate between pentan-2-one and pentan-3-one.


Alkenes   and carbonyl compounds , both contain a π bond but alkenes show electrophilic addition reactions whereas carbonyl compounds show nucleophilic addition reactions. Explain.


Which one of the following gives only one monochloro derivative?


Grignard reagent on reaction with acetone forms.


Paraldehyde is formed as a result of polymerisation:-


The most stable reagent for the conversion of R – CH2OH → RCHO is


The increasing order of the following compounds towards HCN addition is:

(i)
(ii)
(iii)
(iv)

Out of p-tolualdehyde and p-nitrobenzaldehyde, which one is more reactive towards nucleophilic addition reactions, why?


Draw the structure of the following derivative.

The ethylene ketal of hexane-3-one


The product of the following reaction is

\[\begin{array}{cc}
\ce{O}\phantom{.........}\\
||\phantom{.........}\\
\ce{C2H5 - C - CH3 ->[H2/Ni][\Delta] \phantom{..}?}\end{array}\]


Draw the structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw the structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw the structure of the following derivative.

Acetaldehydedimethylacetal


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one 


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