Advertisements
Advertisements
प्रश्न
The product of the following reaction is
\[\begin{array}{cc}
\ce{O}\phantom{.........}\\
||\phantom{.........}\\
\ce{C2H5 - C - CH3 ->[H2/Ni][\Delta] \phantom{..}?}\end{array}\]
पर्याय
\[\ce{CH3 - CH2 - CH2 - CH2 - OH}\]
\[\begin{array}{cc}
\ce{CH3 - CH - CH2 - CH3}\\
|\phantom{.........}\\
\ce{OH}\phantom{.......}
\end{array}\]\[\ce{CH3 - CH2 - CH2 - CH3}\]
\[\ce{CH3 - CH2 - CH2 - COOH}\]
Advertisements
उत्तर
\[\begin{array}{cc}
\ce{CH3 - CH - CH2 - CH3}\\
|\phantom{.........}\\
\ce{OH}\phantom{.......}
\end{array}\]
Explanation:
\[\begin{array}{cc}
\ce{O}\phantom{...............................}\\
||\phantom{...............................}\\
\ce{\underset{(2-Butanone)}{C2H5 - C - CH3} ->[H2/Ni][\Delta]\phantom{..} CH3 - CH - CH2 CH3}\\
\phantom{....................}|\\
\phantom{......................}\ce{\underset{(2-Butanol)}{OH}}\\
\end{array}\]
APPEARS IN
संबंधित प्रश्न
How are the following compounds prepared?
benzaldehyde from benzene
Arrange the following compound in increasing order of its reactivity in nucleophilic addition reactions.
Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.
Hint: Consider steric effect and electronic effect.
What is meant by the following term? Give an example of the reaction in the following case.
Acetal
What is meant by the following term? Give an example of the reaction in the following case.
Ketal
What is meant by the following term? Give an example of the reaction in the following case.
2, 4-DNP-derivative
What is meant by the following term? Give an example of the reaction in the following case.
Schiff’s base
Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards HCN)
How will you bring about the following conversion in not more than two steps?
Bromobenzene to 1-Phenylethanol
How are the following compounds prepared?
acetophenone from benzene
What is the action of the following reagents on ethanoic acid?
1) `LiAlH_4"/"H_3O^+`
2) `PCl_3 , "heat"`
3) `P_2O_5, "heat"`
Write the main product formed when propanal reacts with the following reagents:
H2N- NH2 followed by heating with KOH in ethylene glycol.
Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):
(i) 
(ii) 
(iii) 
(iv) 
Identify the compounds A, B and C in the following reaction.
\[\ce{CH3 - Br ->[Mg/ether] (A) ->[(i) CO][(ii) Water] (B) ->[CH3OH/H+][Δ] (C)}\]
The most stable reagent for the conversion of R – CH2OH → RCHO is
What happens when ethanal is treated with excess ethanol and acid?
Which of the following is most reactive in nucleophilic addition reactions?
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Out of p-tolualdehyde and p-nitrobenzaldehyde, which one is more reactive towards nucleophilic addition reactions, why?
Draw the structure of the following derivative.
The ethylene ketal of hexane-3-one
Draw structure of the following derivative.
Acetaldehydedimethylacetal
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw structures of the following derivative.
The ethylene ketal of hexan-3-one
Draw the structure of the following derivative.
Acetaldehydedimethylacetal
Draw the structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw the structure of the following derivative.
Acetaldehydedimethylacetal
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Give an example of the reaction in the following case.
Oxime
The major product of the following reaction is:
Complete the following reaction:
[C] is __________.
