Advertisements
Advertisements
प्रश्न
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
Excess ethanol and acid
Advertisements
उत्तर
APPEARS IN
संबंधित प्रश्न
Draw the structure of the semicarbazone of ethanal.
Write the structures of the main products when acetone (CH3 − CO − CH3) reacts with the following reagent :
H2N − NHCONH2/H+
Arrange the following compound in increasing order of its reactivity in nucleophilic addition reactions.
Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.
Hint: Consider steric effect and electronic effect.
Predict the product of the following reaction:
What is meant by the following term? Give an example of the reaction in the following case.
2, 4-DNP-derivative
What is meant by the following term? Give an example of the reaction in the following case.
Schiff’s base
How are the following compounds prepared?
benzaldehyde from benzoyl chloride
Write balanced chemical equations for action of ammonia on - acetaldehyde
Write balanced chemical equations for action of ammonia on - acetone
Write balanced chemical equations for action of ammonia on - acetone
Give a simple chemical test to distinguish between 
Which one of the following gives only one monochloro derivative?
Grignard reagent on reaction with acetone forms.
The most stable reagent for the conversion of R – CH2OH → RCHO is
What is the action of sodium hypoiodite on acetone?
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Draw the structure of the following derivative.
The ethylene ketal of hexane-3-one
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
