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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Write Balanced Chemical Equations for Action of Ammonia on - Acetone - Chemistry

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प्रश्न

Write balanced chemical equations for action of ammonia on - acetone

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उत्तर

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2013-2014 (October)

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व्हिडिओ ट्यूटोरियलVIEW ALL [1]

संबंधित प्रश्‍न

Acetaldehyde, when treated with which among the following reagents does NOT undergo addition reaction?

(A) Ammonia

(B) Hydroxylamine

(C) Ammoniacal silver nitrate

(D) Semicarbazide


Write the products formed when CH3CHO reacts with the following reagents : H2N – OH


Arrange the following compound in increasing order of its reactivity in nucleophilic addition reactions.

Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.

Hint: Consider steric effect and electronic effect.


Predict the product of the following reaction:


How will you bring about the following conversion in not more than two steps?

Bromobenzene to 1-Phenylethanol


Complete the synthesis by giving missing starting material, reagent or product.


How are the following compounds prepared?

acetophenone from benzene


Write the structure of Phenylmethanamine.


How will you convert sodium acetate to methane?


Give a simple chemical test to distinguish between 
 


Write the main product formed when propanal reacts with the following reagents: 
2 moles of 3 CH OH in presence of dry HCl 


Which of the following compounds is most reactive towards nucleophilic addition reactions?


Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):

(i)  

(ii)  

(iii)  

(iv) 


Reaction of aqueous sodium hydroxide on chlorobenzene gives which of the following products?


A Idol condensation will not be observed in


Acetaldehyde and acetone differ in their reaction with


What happens when propanone is treated with CH3MgBr and then hydrolysed?


The product "P" in the above reaction is:


The following questions are case-based questions. Read the passage carefully and answer the questions that follow:

The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols.

Answer the following:

(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)

(b) Why carboxylic acid is a stronger acid than phenol? (1)

(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)

CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\],  \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]

(ii) Write a chemical test to distinguish between propanal and propanone. (1)

OR

(c) Write the main product in the following: (2)

(i)
(ii)

Write the structure of the product formed when acetone reacts with 2, 4 DNP reagent.


Draw structures of the given derivatives.

The ethylene ketal of hexan-3-one


The product of the following reaction is

\[\begin{array}{cc}
\ce{O}\phantom{.........}\\
||\phantom{.........}\\
\ce{C2H5 - C - CH3 ->[H2/Ni][\Delta] \phantom{..}?}\end{array}\]


Draw the structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw structure of the following derivative:

Acetaldehydedimethylacetal


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw structures of the given derivatives.

The ethylene ketal of hexan-3-one


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one


Give an example of the reaction in the following case.

Oxime


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