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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Write Balanced Chemical Equations for Action of Ammonia on - Acetone

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प्रश्न

Write balanced chemical equations for action of ammonia on - acetone

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उत्तर

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  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
2013-2014 (October)

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व्हिडिओ ट्यूटोरियलVIEW ALL [1]

संबंधित प्रश्‍न

Acetaldehyde, when treated with which among the following reagents does NOT undergo addition reaction?

(A) Ammonia

(B) Hydroxylamine

(C) Ammoniacal silver nitrate

(D) Semicarbazide


Predict the products of the following reactions:

 


What is meant by the following term? Give an example of the reaction in the following case.

Acetal


What is meant by the following term? Give an example of the reaction in the following case.

Semicarbazone


What is meant by the following term? Give an example of the reaction in the following case.

Imine


Arrange the following compounds in increasing order of their property as indicated:

Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards HCN)


Give plausible explanation for the following:

Cyclohexanone forms cyanohydrin in good yield but 2, 2, 6 trimethylcyclohexanone does not.


Write balanced chemical equations for action of ammonia on - acetaldehyde


Write the main product formed when propanal reacts with the following reagents: 
2 moles of 3 CH OH in presence of dry HCl 


Write the main product formed when propanal reacts with the following reagents: 
H2N- NH2  followed by heating with KOH in ethylene glycol.


 Acetone, Acetaldehyde, Benzaldehyde, Acetophenone – reactivity towards addition of HCN. 


Alkenes   and carbonyl compounds , both contain a π bond but alkenes show electrophilic addition reactions whereas carbonyl compounds show nucleophilic addition reactions. Explain.


Paraldehyde is formed as a result of polymerisation:-


Which among the following is most reactive to give nucleophilic addition?


What is the action of sodium hypoiodite on acetone?


Arrange the following in the increasing order of their property indicated:

Ethanal, Propanone, Propanal, Butanone (reactivity towards nucleophilic addition)


The increasing order of the following compounds towards HCN addition is:

(i)
(ii)
(iii)
(iv)

The following questions are case-based questions. Read the passage carefully and answer the questions that follow:

The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols.

Answer the following:

(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)

(b) Why carboxylic acid is a stronger acid than phenol? (1)

(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)

CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\],  \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]

(ii) Write a chemical test to distinguish between propanal and propanone. (1)

OR

(c) Write the main product in the following: (2)

(i)
(ii)

Draw the structure of the following derivative.

The ethylene ketal of hexane-3-one


Draw structure of the following derivative.

The ethylene ketal of hexane-3-one


Draw structure of the following derivative.

Acetaldehydedimethylacetal


Draw structures of the following derivative.

The ethylene ketal of hexan-3-one


Draw the structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one 


Which of the following will not be formed when calcium formate is distilled with calcium acetate?


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