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प्रश्न
Acetaldehyde, when treated with which among the following reagents does NOT undergo addition reaction?
(A) Ammonia
(B) Hydroxylamine
(C) Ammoniacal silver nitrate
(D) Semicarbazide
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उत्तर
(C) Ammoniacal silver nitrate
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संबंधित प्रश्न
Write balanced chemical equations for action of ammonia on - formaldehyde
Write the products formed when CH3CHO reacts with the following reagents : H2N – OH
Predict the product of the following reaction:
\[\begin{array}{cc}
\phantom{..............}\ce{O}\\
\phantom{..............}||\\
\ce{R - CH = CH - CHO + NH2 - C - NH - NH2 ->[H+]}\end{array}\]
What is meant by the following term? Give an example of the reaction in the following case.
Semicarbazone
What is meant by the following term? Give an example of the reaction in the following case.
Hemiacetal
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PhMgBr and then H3O+
How will you bring about the following conversion in not more than two steps?
Bromobenzene to 1-Phenylethanol
Give plausible explanation for the following:
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Write balanced chemical equations for action of ammonia on - acetone
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A Idol condensation will not be observed in
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\[\ce{CH3 - CH = CH - CH2 - CHO ->[i) LiAlH4][ii) H3O+]}\] ______?
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Draw the structure of the following derivative.
The ethylene ketal of hexane-3-one
Draw structure of the following derivative.
The ethylene ketal of hexane-3-one
Draw structures of the following derivative.
The ethylene ketal of hexan-3-one
Draw the structure of the following derivative.
Acetaldehydedimethylacetal
Draw the structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw the structure of the following derivative.
Acetaldehydedimethylacetal
Draw structures of the given derivatives.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw the structure of the given derivative.
The ethylene ketal of hexan-3-one
