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प्रश्न
Predict the product of the following reaction:
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उत्तर
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संबंधित प्रश्न
Acetaldehyde, when treated with which among the following reagents does NOT undergo addition reaction?
(A) Ammonia
(B) Hydroxylamine
(C) Ammoniacal silver nitrate
(D) Semicarbazide
Write balanced chemical equations for action of ammonia on - formaldehyde
Arrange the following in the increasing order of their reactivity towards nucleophilic addition reaction:
C6H5COCH3, CH3-CHO, CH3COCH3
Write the structures of the main products when acetone (CH3 − CO − CH3) reacts with the following reagent :
H2N − NHCONH2/H+
Write the products formed when CH3CHO reacts with the following reagents : HCN
What is meant by the following term? Give an example of the reaction in the following case.
Imine
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
PhMgBr and then H3O+
Give plausible explanation for the following:
There are two −NH2 groups in semicarbazide. However, only one is involved in the formation of semicarbazones.
How are the following compounds prepared?
acetophenone from benzene
How are the following compounds prepared?
benzaldehyde from benzoyl chloride
Write the main product formed when propanal reacts with the following reagents:
2 moles of 3 CH OH in presence of dry HCl
Write the main product formed when propanal reacts with the following reagents:
H2N- NH2 followed by heating with KOH in ethylene glycol.
Which of the following compounds is most reactive towards nucleophilic addition reactions?
Alkenes 
and carbonyl compounds 
, both contain a π bond but alkenes show electrophilic addition reactions whereas carbonyl compounds show nucleophilic addition reactions. Explain.
The increasing order of the following compounds towards HCN addition is:
| (i) |  |
| (ii) |  |
| (iii) |  |
| (iv) |  |
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Why dissociation of HCN is suppressed by the addition of HCL?
Draw structures of the given derivatives.
The ethylene ketal of hexan-3-one
Give an example of the reaction in the following case.
Oxime
