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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Predict the product of the following reaction: O + NH2—NH O2N NO2 - Chemistry

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प्रश्न

Predict the product of the following reaction:

रासायनिक समीकरण/संरचनाएँ
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उत्तर

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अध्याय 8: Aldehydes, Ketones and Carboxylic Acids - Intext Questions [पृष्ठ २४३]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 8 Aldehydes, Ketones and Carboxylic Acids
Intext Questions | Q 8.5 (ii) | पृष्ठ २४३

संबंधित प्रश्न

Acetaldehyde, when treated with which among the following reagents does NOT undergo addition reaction?

(A) Ammonia

(B) Hydroxylamine

(C) Ammoniacal silver nitrate

(D) Semicarbazide


How are the following compounds prepared?

benzaldehyde from benzene


Predict the products of the following reactions:

 


What is meant by the following term? Give an example of the reaction in the following case.

Imine


Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.

PhMgBr and then H3O+


Complete the synthesis by giving missing starting material, reagent or product.

\[\ce{C6H5CHO ->[H2NCONHNH2]}\]


Give a simple chemical test to distinguish between 
 


Write the main product formed when propanal reacts with the following reagents: 
H2N- NH2  followed by heating with KOH in ethylene glycol.


How will you convert benzoic acid to m-bromobenzoic acid?


Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):

(i)  

(ii)  

(iii)  

(iv) 


Carboxylic acids contain carbonyl group but do not show the nucleophilic addition reaction like aldehydes or ketones. Why?


Grignard reagent on reaction with acetone forms.


Arrange the following in the increasing order of their property indicated:

Ethanal, Propanone, Propanal, Butanone (reactivity towards nucleophilic addition)


Which will undergo faster nucleophilic addition reaction?

Acetaldehyde or Propanone


The following questions are case-based questions. Read the passage carefully and answer the questions that follow:

The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols.

Answer the following:

(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)

(b) Why carboxylic acid is a stronger acid than phenol? (1)

(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)

CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\],  \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]

(ii) Write a chemical test to distinguish between propanal and propanone. (1)

OR

(c) Write the main product in the following: (2)

(i)
(ii)

The product of the following reaction is

\[\begin{array}{cc}
\ce{O}\phantom{.........}\\
||\phantom{.........}\\
\ce{C2H5 - C - CH3 ->[H2/Ni][\Delta] \phantom{..}?}\end{array}\]


Draw the structure of the following derivative.

Acetaldehydedimethylacetal


Draw the structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw the structure of the given derivative.

The ethylene ketal of hexan-3-one


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