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प्रश्न
How will you convert benzoic acid to m-bromobenzoic acid?
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उत्तर
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संबंधित प्रश्न
Write the structures of the main products when acetone (CH3 − CO − CH3) reacts with the following reagent :
H2N − NHCONH2/H+
Write the products formed when CH3CHO reacts with the following reagents : HCN
Predict the product of the following reaction:
What is meant by the following term? Give an example of the reaction in the following case.
2, 4-DNP-derivative
What is meant by the following term? Give an example of the reaction in the following case.
Schiff’s base
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
PhMgBr and then H3O+
How are the following compounds prepared?
acetophenone from benzene
Write balanced chemical equations for action of ammonia on - acetone
Write the structure of Phenylmethanamine.
How will you convert sodium acetate to methane?
Give a simple chemical test to distinguish between 
Write the main product formed when propanal reacts with the following reagents:
2 moles of 3 CH OH in presence of dry HCl
Acetone, Acetaldehyde, Benzaldehyde, Acetophenone – reactivity towards addition of HCN.
Carboxylic acids contain carbonyl group but do not show the nucleophilic addition reaction like aldehydes or ketones. Why?
Reaction of aqueous sodium hydroxide on chlorobenzene gives which of the following products?
The pH of blood does not appreciably change by a small addition of acid or base because
Which one of the following gives only one monochloro derivative?
Paraldehyde is formed as a result of polymerisation:-
What happens when propanone is treated with CH3MgBr and then hydrolysed?
What happens when ethanal is treated with excess ethanol and acid?
In the following reaction
\[\ce{Carbonyl compound + MeOH <=>[HCl] acetal}\]
Rate of the reaction is the highest for ______.
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Write the structure of the product formed when acetone reacts with 2, 4 DNP reagent.
Draw structures of the given derivatives.
The ethylene ketal of hexan-3-one
Draw structures of the given derivatives.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative.
Acetaldehydedimethylacetal
Why dissociation of HCN is suppressed by the addition of HCL?
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
