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प्रश्न
What are amines?
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उत्तर
Amines are the organic derivatives of ammonia in which one, two or all the three hydrogens atoms attached to nitrogen are replaced by equivalent number of same or diferent alkyl or aryl group.
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संबंधित प्रश्न
Draw the structure of the semicarbazone of ethanal.
Write the structures of the main products when acetone (CH3 − CO − CH3) reacts with the following reagent :
H2N − NHCONH2/H+
Write the products formed when CH3CHO reacts with the following reagents : HCN
Predict the product of the following reaction:
What is meant by the following term? Give an example of the reaction in the following case.
Ketal
How will you bring about the following conversion in not more than two steps?
Bromobenzene to 1-Phenylethanol
Give plausible explanation for the following:
Cyclohexanone forms cyanohydrin in good yield but 2, 2, 6 trimethylcyclohexanone does not.
Give plausible explanation for the following:
There are two −NH2 groups in semicarbazide. However, only one is involved in the formation of semicarbazones.
Write balanced chemical equations for action of ammonia on - acetone
Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):
(i) 
(ii) 
(iii) 
(iv) 
The most stable reagent for the conversion of R – CH2OH → RCHO is
Which among the following is most reactive to give nucleophilic addition?
Write the name of product formed, when acetone is treated with 2, 4-dinitrophenyl hydrazine.
What is the action of sodium hypoiodite on acetone?
Arrange the following in the increasing order of their property indicated:
Ethanal, Propanone, Propanal, Butanone (reactivity towards nucleophilic addition)
Which of the following is most reactive in nucleophilic addition reactions?
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Draw structure of the following derivative.
Acetaldehydedimethylacetal
Why dissociation of HCN is suppressed by the addition of HCL?
Draw the structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw the structure of the given derivative.
The ethylene ketal of hexan-3-one
Give an example of the reaction in the following case.
Oxime
Give an example of the reaction in the following case.
Imine
Which of the following will not be formed when calcium formate is distilled with calcium acetate?
The major product of the following reaction is:
Complete the following reaction:
[C] is __________.
