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प्रश्न
Write the name of product formed, when acetone is treated with 2, 4-dinitrophenyl hydrazine.
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उत्तर
2, 4 - Dinitrophenyl hydrazone is formed when acetone is treated with 2, 4- dinitrophenyl hydrazine.
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संबंधित प्रश्न
Predict the products of the following reactions:
Arrange the following compound in increasing order of its reactivity in nucleophilic addition reactions.
Ethanal, Propanal, Propanone, Butanone.
Hint: Consider steric effect and electronic effect.
Predict the product of the following reaction:
What is meant by the following term? Give an example of the reaction in the following case.
Semicarbazone
What is meant by the following term? Give an example of the reaction in the following case.
Hemiacetal
What is meant by the following term? Give an example of the reaction in the following case.
Oxime
Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone (reactivity towards HCN)
Give plausible explanation for the following:
Cyclohexanone forms cyanohydrin in good yield but 2, 2, 6 trimethylcyclohexanone does not.
Explain the mechanism of alkaline hydrolysis of tert-butyl bromide with energy profile diagram.
Write balanced chemical equations for action of ammonia on - acetaldehyde
Write balanced chemical equations for action of ammonia on - acetone
What are amines?
Acetone, Acetaldehyde, Benzaldehyde, Acetophenone – reactivity towards addition of HCN.
How will you convert benzoic acid to m-bromobenzoic acid?
Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):
(i) 
(ii) 
(iii) 
(iv) 
The pH of blood does not appreciably change by a small addition of acid or base because
Which of the following has the most acidic hydrogen?
A Idol condensation will not be observed in
Acetaldehyde and acetone differ in their reaction with
Arrange the following in the increasing order of their property indicated:
Ethanal, Propanone, Propanal, Butanone (reactivity towards nucleophilic addition)
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Aldehydes and ketones react with hydroxylamine to form ______.
Write the structure of the product formed when acetone reacts with 2, 4 DNP reagent.
Draw structure of the following derivative.
The ethylene ketal of hexane-3-one
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
The product of the following reaction is
\[\begin{array}{cc}
\ce{O}\phantom{.........}\\
||\phantom{.........}\\
\ce{C2H5 - C - CH3 ->[H2/Ni][\Delta] \phantom{..}?}\end{array}\]
Draw structure of the following derivative:
Acetaldehydedimethylacetal
Draw structure of the following derivative:
Acetaldehydedimethylacetal
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
