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प्रश्न
Write the name of product formed, when acetone is treated with 2, 4-dinitrophenyl hydrazine.
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उत्तर
2, 4 - Dinitrophenyl hydrazone is formed when acetone is treated with 2, 4- dinitrophenyl hydrazine.
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संबंधित प्रश्न
Predict the products of the following reactions:
Write the products formed when CH3CHO reacts with the following reagents : HCN
Write the products formed when CH3CHO reacts with the following reagents : H2N – OH
Arrange the following compound in increasing order of its reactivity in nucleophilic addition reactions.
Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.
Hint: Consider steric effect and electronic effect.
Predict the product of the following reaction:
What is meant by the following term? Give an example of the reaction in the following case.
Hemiacetal
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
Semicarbazide and weak acid
Give plausible explanation for the following:
There are two −NH2 groups in semicarbazide. However, only one is involved in the formation of semicarbazones.
Explain the mechanism of alkaline hydrolysis of tert-butyl bromide with energy profile diagram.
Write balanced chemical equations for action of ammonia on - acetaldehyde
Write balanced chemical equations for action of ammonia on - acetone
Write a test to differentiate between pentan-2-one and pentan-3-one.
Alkenes 
and carbonyl compounds 
, both contain a π bond but alkenes show electrophilic addition reactions whereas carbonyl compounds show nucleophilic addition reactions. Explain.
Carboxylic acids contain carbonyl group but do not show the nucleophilic addition reaction like aldehydes or ketones. Why?
Reaction of aqueous sodium hydroxide on chlorobenzene gives which of the following products?
The pH of blood does not appreciably change by a small addition of acid or base because
Which one of the following gives only one monochloro derivative?
Grignard reagent on reaction with acetone forms.
A Idol condensation will not be observed in
Arrange the following in the increasing order of their property indicated:
Ethanal, Propanone, Propanal, Butanone (reactivity towards nucleophilic addition)
The product "P" in the above reaction is:
The increasing order of the following compounds towards HCN addition is:
| (i) |  |
| (ii) |  |
| (iii) |  |
| (iv) |  |
In the following reaction
\[\ce{Carbonyl compound + MeOH <=>[HCl] acetal}\]
Rate of the reaction is the highest for ______.
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Draw structures of the following derivatives.
Acetaldehydedimethylacetal
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Give an example of the reaction in the following case.
Oxime
