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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Complete the synthesis by giving missing starting material, reagent or product. CHO COOH ->[NaCN/HCl]

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प्रश्न

Complete the synthesis by giving missing starting material, reagent or product.

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पाठ 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ २५७]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.17 (vi) | पृष्ठ २५७

संबंधित प्रश्‍न

How are the following compounds prepared?

benzaldehyde from benzene


Predict the products of the following reactions:

 


Predict the product of the following reaction:


What is meant by the following term? Give an example of the reaction in the following case.

Oxime


What is meant by the following term? Give an example of the reaction in the following case.

Schiff’s base


Complete the synthesis by giving missing starting material, reagent or product.

\[\ce{C6H5CHO ->[H2NCONHNH2]}\]


How will you convert sodium acetate to methane?


Write the main product formed when propanal reacts with the following reagents: 
H2N- NH2  followed by heating with KOH in ethylene glycol.


Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):

(i)  

(ii)  

(iii)  

(iv) 


Benzaldehyde can be obtained from benzal chloride. Write reactions for obtaining benzalchloride and then benzaldehyde from it.


The pH of blood does not appreciably change by a small addition of acid or base because


Which of the following has the most acidic hydrogen?


In the following reaction

\[\ce{Carbonyl compound + MeOH <=>[HCl] acetal}\]

Rate of the reaction is the highest for ______.


The following questions are case-based questions. Read the passage carefully and answer the questions that follow:

The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols.

Answer the following:

(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)

(b) Why carboxylic acid is a stronger acid than phenol? (1)

(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)

CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\],  \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]

(ii) Write a chemical test to distinguish between propanal and propanone. (1)

OR

(c) Write the main product in the following: (2)

(i)
(ii)

Write the structure of the product formed when acetone reacts with 2, 4 DNP reagent.


Draw structures of the given derivatives.

The ethylene ketal of hexan-3-one


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one


Give an example of the reaction in the following case.

Oxime


Give an example of the reaction in the following case.

Imine


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