English
Karnataka Board PUCPUC Science 2nd PUC Class 12

Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A): - Chemistry

Advertisements
Advertisements

Question

Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):

(i)  

(ii)  

(iii)  

(iv) 

Short/Brief Note
Advertisements

Solution

(i) 

(ii) 

Explanation:

The given compound is a planar molecule with sp2 hybridized carbon. Carbon atoms are attacked by nucleophiles. If the nucleophile approaches from the front, the (i) and (ii) molecules shift to the front and back positions, respectively and the carbon becomes tetrahedral. Another alternative is that (i) and (ii) molecules will be located above and below the plane, respectively. As a result, the choices (iii) and (iv) aren't represented as planar molecules.

shaalaa.com
  Is there an error in this question or solution?
Chapter 12: Aldehydes, Ketones and Carboxylic Acids - Multiple Choice Questions (Type - I) [Page 172]

APPEARS IN

NCERT Exemplar Chemistry [English] Class 12
Chapter 12 Aldehydes, Ketones and Carboxylic Acids
Multiple Choice Questions (Type - I) | Q 18 | Page 172

RELATED QUESTIONS

How are the following compounds prepared?

benzaldehyde from benzene


Arrange the following in the increasing order of their reactivity towards nucleophilic addition reaction:

C6H5COCH3, CH3-CHO, CH3COCH3


Predict the products of the following reactions:

 


Arrange the following compound in increasing order of its reactivity in nucleophilic addition reactions.

Ethanal, Propanal, Propanone, Butanone.

Hint: Consider steric effect and electronic effect.


Predict the product of the following reaction:

\[\begin{array}{cc}
\phantom{..............}\ce{O}\\
\phantom{..............}||\\
\ce{R - CH = CH - CHO + NH2 - C - NH - NH2 ->[H+]}\end{array}\]


What is meant by the following term? Give an example of the reaction in the following case.

Oxime


What is meant by the following term? Give an example of the reaction in the following case.

Ketal


How will you bring about the following conversion in not more than two steps?

Bromobenzene to 1-Phenylethanol


Write the main product formed when propanal reacts with the following reagents: 
2 moles of 3 CH OH in presence of dry HCl 


Alkenes   and carbonyl compounds , both contain a π bond but alkenes show electrophilic addition reactions whereas carbonyl compounds show nucleophilic addition reactions. Explain.


The pH of blood does not appreciably change by a small addition of acid or base because


Which among the following is most reactive to give nucleophilic addition?


What is the action of sodium hypoiodite on acetone?


Write the structure of the product formed when acetone reacts with 2, 4 DNP reagent.


Why dissociation of HCN is suppressed by the addition of HCL?


The product of the following reaction is

\[\begin{array}{cc}
\ce{O}\phantom{.........}\\
||\phantom{.........}\\
\ce{C2H5 - C - CH3 ->[H2/Ni][\Delta] \phantom{..}?}\end{array}\]


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw structures of the following derivatives.

Acetaldehydedimethylacetal


Draw the structure of the given derivative.

The ethylene ketal of hexan-3-one


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×