Advertisements
Advertisements
Question
Write the products formed when CH3CHO reacts with the following reagents : HCN
Advertisements
Solution 1
Acetaldehyde (CH3CHO) reacts with hydrogen cyanide HCN to give 2-Hydroxypropapanenitrile as product.

Solution 2
Acetaldehyde add a molecule of hydrogen to form acetaldehyde cyanohydrin.

APPEARS IN
RELATED QUESTIONS
What is meant by the following term? Give an example of the reaction in the following case.
Cyanohydrin
What is meant by the following term? Give an example of the reaction in the following case.
Acetal
Explain the mechanism of alkaline hydrolysis of tert-butyl bromide with energy profile diagram.
Acetaldehyde and acetone differ in their reaction with
Arrange the following in the increasing order of their property indicated:
Ethanal, Propanone, Propanal, Butanone (reactivity towards nucleophilic addition)

The product "P" in the above reaction is:
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) | ![]() |
| (ii) | ![]() |
Write the structure of the product formed when acetone reacts with 2, 4 DNP reagent.
Draw the structure of the following derivative.
Acetaldehydedimethylacetal
Draw the structure of the following derivative.
The ethylene ketal of hexan-3-one


