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Ostwald's Dilution Law

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Estimated time: 3 minutes
Maharashtra State Board: Class 12

Law: Ostwald's Dilution Law

The degree of dissociation of a weak electrolyte is inversely proportional to the square root of its concentration.

Feature Weak Acid Weak Base
Dissociation HA ⇌ H⁺ + A⁻ BOH ⇌ B⁺ + OH⁻
Constant Acid dissociation constant (Ka) Base dissociation constant (Kb)
Expression \[K_{a}=\frac{[H^{+}][A^{-}]}{[HA]}\] \[K_{b}=\frac{[B^{+}][OH^{-}]}{[BOH]}\]
Ostwald’s Dilution Law \[\alpha=\sqrt{\frac{K_{a}}{C}}\] or \[\alpha=\sqrt{K_{a}\cdot V}\] \[\alpha=\sqrt{\frac{K_{b}}{C}}\] or \[\alpha=\sqrt{K_{b}\cdot V}\]
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