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Karnataka Board PUCPUC Science 2nd PUC Class 12

PUC Science 2nd PUC Class 12 - Karnataka Board PUC Question Bank Solutions for Chemistry

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Chemistry
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Write reactions of the final alkylation product of aniline with excess of methyl iodide in the presence of sodium carbonate solution.

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Write chemical reaction of aniline with benzoyl chloride and write the name of the product obtained. 

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

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Write structures of different isomers corresponding to the molecular formula C3H9N. Write the IUPAC names of the isomers which will liberate nitrogen gas on treatment with nitrous acid.

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

How will you convert ethanal into the following compound?

But-2-enoic acid

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Give a simple chemical test to distinguish between the following pair of compounds:

Acetophenone and Benzophenone

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Give a simple chemical test to distinguish between the following pair of compounds:

Phenol and Benzoic acid

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Give a simple chemical test to distinguish between the following pair of compounds:

Benzoic acid and Ethyl benzoate

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Give a simple chemical test to distinguish between the following pair of compounds:

Pentan-2-one and Pentan-3-one

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Give a simple chemical test to distinguish between the following pair of compounds:

Benzaldehyde and Acetophenone

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

An organic compound contains 69.77% carbon, 11.63% hydrogen and rest oxygen. The molecular mass of the compound is 86. It does not reduce Tollens’ reagent but forms an addition compound with sodium hydrogensulphite and give positive iodoform test. On vigorous oxidation it gives ethanoic and propanoic acid. Write the possible structure of the compound.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Complete the synthesis by giving missing starting material, reagent or product.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Which alkyl halide from the following pair would you expect to react more rapidly by an SN2 mechanism? Explain your answer.

CH3CH2CH2CH2Br or \[\begin{array}{cc}
\ce{CH3CH2CHCH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{Br}\ 
\end{array}\]

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

In the following pair of halogen compounds, which compound undergoes a faster SN1 reaction?

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

In the following pair of halogen compounds, which compound undergoes a faster SN1 reaction?

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Write the isomers of the compound having the formula C4H9Br.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

What are ambident nucleophiles? Explain with an example.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Which compound in the following pair will react faster in SN2 reaction with OH?

CH3Br or CH3I

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Which compound in the following pair will react faster in SN2 reaction with OH?

(CH3)3CCl or CH3Cl

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

How will you bring about the following conversion?

Toluene to benzyl alcohol

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Write the structure of the major organic product in the following reaction:

\[\ce{CH3CH(Br)CH2CH3 + NaOH ->[water]}\]

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined
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